2,4,5-Trichlorobiphenyl

Izabela Kania-Korwel; Sean Parkin; Larry W. Robertson; Hans Joachim Lehmler

doi:10.1107/S1600536804020975

2,4,5-Trichlorobiphenyl

Izabela Kania-Korwel
, Sean Parkin
, Larry W. Robertson
, Hans Joachim Lehmler

Chemistry

Research output: Contribution to journal › Article › peer-review

8 Scopus citations

Abstract

The chemical structure and properties of 2,4,5-Trichlorobiphenyl were investigated. The dihedral angle between the benzene rings in the compound, C₁₂H₇Cl₃, was 47.25 (4)°. This compound was synthesized in 52% yield by the Suzuki coupling of 2,4,5-trichlorobenzene withe phenylboronic acid. The results show that dihedral angle of the dihydroxy polychlorinated biphenyls (PCB) bound to protein was 30°, while the calculated solution and the solid-state dihedral angle of the neat dihydroxy PCB were 42 and O°.

Original language	English
Pages (from-to)	o1652-o1653
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	60
Issue number	9
DOIs	https://doi.org/10.1107/S1600536804020975
State	Published - Sep 2004

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

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title = "2,4,5-Trichlorobiphenyl",

abstract = "The chemical structure and properties of 2,4,5-Trichlorobiphenyl were investigated. The dihedral angle between the benzene rings in the compound, C12H7Cl3, was 47.25 (4)°. This compound was synthesized in 52\% yield by the Suzuki coupling of 2,4,5-trichlorobenzene withe phenylboronic acid. The results show that dihedral angle of the dihydroxy polychlorinated biphenyls (PCB) bound to protein was 30°, while the calculated solution and the solid-state dihedral angle of the neat dihydroxy PCB were 42 and O°.",

author = "Izabela Kania-Korwel and Sean Parkin and Robertson, \{Larry W.\} and Lehmler, \{Hans Joachim\}",

year = "2004",

month = sep,

doi = "10.1107/S1600536804020975",

language = "English",

volume = "60",

pages = "o1652--o1653",

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TY - JOUR

T1 - 2,4,5-Trichlorobiphenyl

AU - Kania-Korwel, Izabela

AU - Parkin, Sean

AU - Robertson, Larry W.

AU - Lehmler, Hans Joachim

PY - 2004/9

Y1 - 2004/9

N2 - The chemical structure and properties of 2,4,5-Trichlorobiphenyl were investigated. The dihedral angle between the benzene rings in the compound, C12H7Cl3, was 47.25 (4)°. This compound was synthesized in 52% yield by the Suzuki coupling of 2,4,5-trichlorobenzene withe phenylboronic acid. The results show that dihedral angle of the dihydroxy polychlorinated biphenyls (PCB) bound to protein was 30°, while the calculated solution and the solid-state dihedral angle of the neat dihydroxy PCB were 42 and O°.

AB - The chemical structure and properties of 2,4,5-Trichlorobiphenyl were investigated. The dihedral angle between the benzene rings in the compound, C12H7Cl3, was 47.25 (4)°. This compound was synthesized in 52% yield by the Suzuki coupling of 2,4,5-trichlorobenzene withe phenylboronic acid. The results show that dihedral angle of the dihydroxy polychlorinated biphenyls (PCB) bound to protein was 30°, while the calculated solution and the solid-state dihedral angle of the neat dihydroxy PCB were 42 and O°.

UR - https://www.scopus.com/pages/publications/18444369366

UR - https://www.scopus.com/pages/publications/18444369366#tab=citedBy

U2 - 10.1107/S1600536804020975

DO - 10.1107/S1600536804020975

M3 - Article

AN - SCOPUS:18444369366

SN - 1600-5368

VL - 60

SP - o1652-o1653

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 9

ER -

2,4,5-Trichlorobiphenyl

Abstract

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