TY - JOUR
T1 - 2,4,6-Trichloroiodobenzene
AU - Kania-Korwel, Izabela
AU - Robertson, Larry W.
AU - Lehmler, Hans Joachim
AU - Parkin, Scan
PY - 2003/11
Y1 - 2003/11
N2 - The crystal structure of 2,4,6-trichloroiodobenzene, C6H 2Cl3I, a precursor of polychlorinated biphenyls (PCB), was investigated. The 2,4,6-trichloroiodobenzene crystals were obtained while attempting to synthesize 2,2′,4,4′,6,6′-hexachlorobiphenyl using a Suzuki coupling reaction. While the 2,4,5-trichloroiodobenzene isomer was extensively disordered in the crystalline state, the title compound was well ordered. White needles were found to form upon recrystallization from methanol.
AB - The crystal structure of 2,4,6-trichloroiodobenzene, C6H 2Cl3I, a precursor of polychlorinated biphenyls (PCB), was investigated. The 2,4,6-trichloroiodobenzene crystals were obtained while attempting to synthesize 2,2′,4,4′,6,6′-hexachlorobiphenyl using a Suzuki coupling reaction. While the 2,4,5-trichloroiodobenzene isomer was extensively disordered in the crystalline state, the title compound was well ordered. White needles were found to form upon recrystallization from methanol.
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U2 - 10.1107/S1600536803022530
DO - 10.1107/S1600536803022530
M3 - Article
AN - SCOPUS:18544378677
SN - 1600-5368
VL - 59
SP - o1770-o1771
JO - Acta Crystallographica Section E: Structure Reports Online
JF - Acta Crystallographica Section E: Structure Reports Online
IS - 11
ER -