2,4,6-Trichloroiodobenzene

Izabela Kania-Korwel; Larry W. Robertson; Hans Joachim Lehmler; Scan Parkin

doi:10.1107/S1600536803022530

2,4,6-Trichloroiodobenzene

Izabela Kania-Korwel, Larry W. Robertson, Hans Joachim Lehmler, Scan Parkin

Chemistry

Research output: Contribution to journal › Article › peer-review

1 Scopus citations

Abstract

The crystal structure of 2,4,6-trichloroiodobenzene, C₆H ₂Cl₃I, a precursor of polychlorinated biphenyls (PCB), was investigated. The 2,4,6-trichloroiodobenzene crystals were obtained while attempting to synthesize 2,2′,4,4′,6,6′-hexachlorobiphenyl using a Suzuki coupling reaction. While the 2,4,5-trichloroiodobenzene isomer was extensively disordered in the crystalline state, the title compound was well ordered. White needles were found to form upon recrystallization from methanol.

Original language	English
Pages (from-to)	o1770-o1771
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	59
Issue number	11
DOIs	https://doi.org/10.1107/S1600536803022530
State	Published - Nov 2003

ASJC Scopus subject areas

Chemistry (all)
Materials Science (all)
Condensed Matter Physics

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title = "2,4,6-Trichloroiodobenzene",

abstract = "The crystal structure of 2,4,6-trichloroiodobenzene, C6H 2Cl3I, a precursor of polychlorinated biphenyls (PCB), was investigated. The 2,4,6-trichloroiodobenzene crystals were obtained while attempting to synthesize 2,2′,4,4′,6,6′-hexachlorobiphenyl using a Suzuki coupling reaction. While the 2,4,5-trichloroiodobenzene isomer was extensively disordered in the crystalline state, the title compound was well ordered. White needles were found to form upon recrystallization from methanol.",

author = "Izabela Kania-Korwel and Robertson, {Larry W.} and Lehmler, {Hans Joachim} and Scan Parkin",

year = "2003",

month = nov,

doi = "10.1107/S1600536803022530",

language = "English",

volume = "59",

pages = "o1770--o1771",

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TY - JOUR

T1 - 2,4,6-Trichloroiodobenzene

AU - Kania-Korwel, Izabela

AU - Robertson, Larry W.

AU - Lehmler, Hans Joachim

AU - Parkin, Scan

PY - 2003/11

Y1 - 2003/11

N2 - The crystal structure of 2,4,6-trichloroiodobenzene, C6H 2Cl3I, a precursor of polychlorinated biphenyls (PCB), was investigated. The 2,4,6-trichloroiodobenzene crystals were obtained while attempting to synthesize 2,2′,4,4′,6,6′-hexachlorobiphenyl using a Suzuki coupling reaction. While the 2,4,5-trichloroiodobenzene isomer was extensively disordered in the crystalline state, the title compound was well ordered. White needles were found to form upon recrystallization from methanol.

AB - The crystal structure of 2,4,6-trichloroiodobenzene, C6H 2Cl3I, a precursor of polychlorinated biphenyls (PCB), was investigated. The 2,4,6-trichloroiodobenzene crystals were obtained while attempting to synthesize 2,2′,4,4′,6,6′-hexachlorobiphenyl using a Suzuki coupling reaction. While the 2,4,5-trichloroiodobenzene isomer was extensively disordered in the crystalline state, the title compound was well ordered. White needles were found to form upon recrystallization from methanol.

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U2 - 10.1107/S1600536803022530

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AN - SCOPUS:18544378677

VL - 59

SP - o1770-o1771

IS - 11

ER -

2,4,6-Trichloroiodobenzene

Abstract

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