3′,4′-Dichloro-biphenyl-4-yl 2,2,2-trichloroethyl sulfate

Xueshu Li; Sean Parkin; Michael W. Duffel; Larry W. Robertson; Hans Joachim Lehmler

doi:10.1107/S1600536810020362

3′,4′-Dichloro-biphenyl-4-yl 2,2,2-trichloroethyl sulfate

Xueshu Li, Sean Parkin, Michael W. Duffel, Larry W. Robertson, Hans Joachim Lehmler

Chemistry

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

The four independent molecules in the asymmetric unit of the title compound, C₁₄H₉Cl₅O₄S, are related by pseudo-inversion centres. The molecules have C_aromatic-O bond lengths ranging from 1.426 (10) to 1.449 (9) Å and biphenyl-4-yl sulfate ester bond lengths ranging from 1.563 (6) to 1.586 (6) Å, which is comparable to structurally related sulfuric acid diesters. The dihedral angles between the benzene rings range from 22.5 (4) to 29.1 (4)° and are significantly smaller than the calculated dihedral angle of 41.2°.

Original language	English
Pages (from-to)	o1615-o1616
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	66
Issue number	7
DOIs	https://doi.org/10.1107/S1600536810020362
State	Published - 2010

ASJC Scopus subject areas

Chemistry (all)
Materials Science (all)
Condensed Matter Physics

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title = "3′,4′-Dichloro-biphenyl-4-yl 2,2,2-trichloroethyl sulfate",

abstract = "The four independent molecules in the asymmetric unit of the title compound, C14H9Cl5O4S, are related by pseudo-inversion centres. The molecules have Caromatic-O bond lengths ranging from 1.426 (10) to 1.449 (9) {\AA} and biphenyl-4-yl sulfate ester bond lengths ranging from 1.563 (6) to 1.586 (6) {\AA}, which is comparable to structurally related sulfuric acid diesters. The dihedral angles between the benzene rings range from 22.5 (4) to 29.1 (4)° and are significantly smaller than the calculated dihedral angle of 41.2°.",

author = "Xueshu Li and Sean Parkin and Duffel, {Michael W.} and Robertson, {Larry W.} and Lehmler, {Hans Joachim}",

year = "2010",

doi = "10.1107/S1600536810020362",

language = "English",

volume = "66",

pages = "o1615--o1616",

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TY - JOUR

T1 - 3′,4′-Dichloro-biphenyl-4-yl 2,2,2-trichloroethyl sulfate

AU - Li, Xueshu

AU - Parkin, Sean

AU - Duffel, Michael W.

AU - Robertson, Larry W.

AU - Lehmler, Hans Joachim

PY - 2010

Y1 - 2010

N2 - The four independent molecules in the asymmetric unit of the title compound, C14H9Cl5O4S, are related by pseudo-inversion centres. The molecules have Caromatic-O bond lengths ranging from 1.426 (10) to 1.449 (9) Å and biphenyl-4-yl sulfate ester bond lengths ranging from 1.563 (6) to 1.586 (6) Å, which is comparable to structurally related sulfuric acid diesters. The dihedral angles between the benzene rings range from 22.5 (4) to 29.1 (4)° and are significantly smaller than the calculated dihedral angle of 41.2°.

AB - The four independent molecules in the asymmetric unit of the title compound, C14H9Cl5O4S, are related by pseudo-inversion centres. The molecules have Caromatic-O bond lengths ranging from 1.426 (10) to 1.449 (9) Å and biphenyl-4-yl sulfate ester bond lengths ranging from 1.563 (6) to 1.586 (6) Å, which is comparable to structurally related sulfuric acid diesters. The dihedral angles between the benzene rings range from 22.5 (4) to 29.1 (4)° and are significantly smaller than the calculated dihedral angle of 41.2°.

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DO - 10.1107/S1600536810020362

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SP - o1615-o1616

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ER -

3′,4′-Dichloro-biphenyl-4-yl 2,2,2-trichloroethyl sulfate

Abstract

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