4′-Chlorobiphenyl-3-yl 2,2,2-trichloro-ethyl sulfate

Xueshu Li; Sean Parkin; Michael W. Duffel; Larry W. Robertson; Hans Joachim Lehmler

doi:10.1107/S1600536810031338

4′-Chlorobiphenyl-3-yl 2,2,2-trichloro-ethyl sulfate

Xueshu Li
, Sean Parkin
, Michael W. Duffel
, Larry W. Robertson
, Hans Joachim Lehmler

Chemistry

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

The title compound, C₁₄H₁₀Cl4O₄S, is a 2,2,2-trichloroethyl-protected precursor of 4′-chlorobiphenyl-3-yl sulfate, a sulfuric acid ester of 4′-chlorobiphenyl-3-ol. The C _aromatic-O and O-S bond lengths of the C_aromatic-O-S unit are comparable to those in structurally analogous biphenyl-4-yl 2,2,2-trichloroethyl sulfates with no electronegative chlorine substituent in the benzene ring with the sulfate ester group. The dihedral angle between the aromatic rings is 27.47 (6)°.

Original language	English
Pages (from-to)	o2306
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	66
Issue number	9
DOIs	https://doi.org/10.1107/S1600536810031338
State	Published - Sep 2010

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

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title = "4′-Chlorobiphenyl-3-yl 2,2,2-trichloro-ethyl sulfate",

abstract = "The title compound, C14H10Cl4O4S, is a 2,2,2-trichloroethyl-protected precursor of 4′-chlorobiphenyl-3-yl sulfate, a sulfuric acid ester of 4′-chlorobiphenyl-3-ol. The C aromatic-O and O-S bond lengths of the Caromatic-O-S unit are comparable to those in structurally analogous biphenyl-4-yl 2,2,2-trichloroethyl sulfates with no electronegative chlorine substituent in the benzene ring with the sulfate ester group. The dihedral angle between the aromatic rings is 27.47 (6)°.",

author = "Xueshu Li and Sean Parkin and Duffel, \{Michael W.\} and Robertson, \{Larry W.\} and Lehmler, \{Hans Joachim\}",

year = "2010",

month = sep,

doi = "10.1107/S1600536810031338",

language = "English",

volume = "66",

pages = "o2306",

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TY - JOUR

T1 - 4′-Chlorobiphenyl-3-yl 2,2,2-trichloro-ethyl sulfate

AU - Li, Xueshu

AU - Parkin, Sean

AU - Duffel, Michael W.

AU - Robertson, Larry W.

AU - Lehmler, Hans Joachim

PY - 2010/9

Y1 - 2010/9

N2 - The title compound, C14H10Cl4O4S, is a 2,2,2-trichloroethyl-protected precursor of 4′-chlorobiphenyl-3-yl sulfate, a sulfuric acid ester of 4′-chlorobiphenyl-3-ol. The C aromatic-O and O-S bond lengths of the Caromatic-O-S unit are comparable to those in structurally analogous biphenyl-4-yl 2,2,2-trichloroethyl sulfates with no electronegative chlorine substituent in the benzene ring with the sulfate ester group. The dihedral angle between the aromatic rings is 27.47 (6)°.

AB - The title compound, C14H10Cl4O4S, is a 2,2,2-trichloroethyl-protected precursor of 4′-chlorobiphenyl-3-yl sulfate, a sulfuric acid ester of 4′-chlorobiphenyl-3-ol. The C aromatic-O and O-S bond lengths of the Caromatic-O-S unit are comparable to those in structurally analogous biphenyl-4-yl 2,2,2-trichloroethyl sulfates with no electronegative chlorine substituent in the benzene ring with the sulfate ester group. The dihedral angle between the aromatic rings is 27.47 (6)°.

UR - https://www.scopus.com/pages/publications/77956319406

UR - https://www.scopus.com/pages/publications/77956319406#tab=citedBy

U2 - 10.1107/S1600536810031338

DO - 10.1107/S1600536810031338

M3 - Article

C2 - 21588655

AN - SCOPUS:77956319406

SN - 1600-5368

VL - 66

SP - o2306

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 9

ER -

4′-Chlorobiphenyl-3-yl 2,2,2-trichloro-ethyl sulfate

Abstract

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