A δ-lactone synthesis involving an intramolecular 1,4-addition of α-iodoacetates to enones

Ayhan S. Demir; Raymond S. Gross; Norma K. Dunlap; A. Bashir-Hashemi; David S. Watt

doi:10.1016/S0040-4039(00)85267-3

A δ-lactone synthesis involving an intramolecular 1,4-addition of α-iodoacetates to enones

Ayhan S. Demir, Raymond S. Gross, Norma K. Dunlap, A. Bashir-Hashemi, David S. Watt

Molecular and Cellular Biochemistry

Research output: Contribution to journal › Article › peer-review

23 Scopus citations

Abstract

A cyclization of δ-(iodoacetoxy)-α,β-unsaturated ketones using iodotrimethylsilane involved a selective 1,4-addition of the acetate subunit to the enone and furnished δ-lactones in good yield.

Original language	English
Pages (from-to)	5567-5570
Number of pages	4
Journal	Tetrahedron Letters
Volume	27
Issue number	46
DOIs	https://doi.org/10.1016/S0040-4039(00)85267-3
State	Published - 1986

ASJC Scopus subject areas

Biochemistry
Drug Discovery
Organic Chemistry

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10.1016/S0040-4039(00)85267-3

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title = "A δ-lactone synthesis involving an intramolecular 1,4-addition of α-iodoacetates to enones",

abstract = "A cyclization of δ-(iodoacetoxy)-α,β-unsaturated ketones using iodotrimethylsilane involved a selective 1,4-addition of the acetate subunit to the enone and furnished δ-lactones in good yield.",

author = "Demir, {Ayhan S.} and Gross, {Raymond S.} and Dunlap, {Norma K.} and A. Bashir-Hashemi and Watt, {David S.}",

year = "1986",

doi = "10.1016/S0040-4039(00)85267-3",

language = "English",

volume = "27",

pages = "5567--5570",

number = "46",

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T1 - A δ-lactone synthesis involving an intramolecular 1,4-addition of α-iodoacetates to enones

AU - Demir, Ayhan S.

AU - Gross, Raymond S.

AU - Dunlap, Norma K.

AU - Bashir-Hashemi, A.

AU - Watt, David S.

PY - 1986

Y1 - 1986

N2 - A cyclization of δ-(iodoacetoxy)-α,β-unsaturated ketones using iodotrimethylsilane involved a selective 1,4-addition of the acetate subunit to the enone and furnished δ-lactones in good yield.

AB - A cyclization of δ-(iodoacetoxy)-α,β-unsaturated ketones using iodotrimethylsilane involved a selective 1,4-addition of the acetate subunit to the enone and furnished δ-lactones in good yield.

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UR - http://www.scopus.com/inward/citedby.url?scp=0000769669&partnerID=8YFLogxK

U2 - 10.1016/S0040-4039(00)85267-3

DO - 10.1016/S0040-4039(00)85267-3

M3 - Article

AN - SCOPUS:0000769669

SN - 0040-4039

VL - 27

SP - 5567

EP - 5570

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 46

ER -

A δ-lactone synthesis involving an intramolecular 1,4-addition of α-iodoacetates to enones

Abstract

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