TY - JOUR
T1 - A (1R,2R,5R)-(+)-2α-hydroxypinan-3-one ketimine
AU - Ayers, Joshua T.
AU - Sonar, Vijayakumar N.
AU - Parking, Sean
AU - Dwoskin, Linda P.
AU - Crooks, Peter A.
PY - 2005/8/1
Y1 - 2005/8/1
N2 - The title compound {systematic name: (1R,2R,5R)-(+)-2-hydroxy-2,6,6- trimethyl-3-[(3-pyridyl)methylimino]bicyclo-[3.1.1]heptane}, C 16H22O, was obtained by the condensation reaction of (1R,2R,5R)-(+)-2α-hydroxypinan-3-one with 3-(aminomethyl)pyridine in the presence of boron trifluoride. The compound was obtained as an enantiomerically pure isomer, and has the 1R,2R,5R configuration. In the crystal structure, molecules are linked together by intermolecular O-H⋯N hydrogen bonds between the hydroxy group of the pinanone group and the N atom of the pyridine ring, forming molecular chains.
AB - The title compound {systematic name: (1R,2R,5R)-(+)-2-hydroxy-2,6,6- trimethyl-3-[(3-pyridyl)methylimino]bicyclo-[3.1.1]heptane}, C 16H22O, was obtained by the condensation reaction of (1R,2R,5R)-(+)-2α-hydroxypinan-3-one with 3-(aminomethyl)pyridine in the presence of boron trifluoride. The compound was obtained as an enantiomerically pure isomer, and has the 1R,2R,5R configuration. In the crystal structure, molecules are linked together by intermolecular O-H⋯N hydrogen bonds between the hydroxy group of the pinanone group and the N atom of the pyridine ring, forming molecular chains.
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U2 - 10.1107/S1600536805023287
DO - 10.1107/S1600536805023287
M3 - Article
AN - SCOPUS:27744549240
SN - 1600-5368
VL - 61
SP - o2682-o2684
JO - Acta Crystallographica Section E: Structure Reports Online
JF - Acta Crystallographica Section E: Structure Reports Online
IS - 8
ER -