A bis(pyrazolyl)borate complex of silicon(IV)

Vicki O. Atwood; David A. Atwood; Alan H. Cowley; Swiatoslaw Trofimenko

doi:10.1016/S0277-5387(00)83330-6

A bis(pyrazolyl)borate complex of silicon(IV)

Vicki O. Atwood, David A. Atwood, Alan H. Cowley, Swiatoslaw Trofimenko

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10 Scopus citations

Abstract

The first pyrazolylborate complex of silicon, [Ph₂B(pz)₂]₂SiCl₂, has been prepared via the reaction of K[Ph₂B(pz)₂] with SiCl₄. The structure of this complex has been determined by X-ray crystallography. The bis(pyrazolyl)borate ligand behaves in a bidentate fashion and the silicon adopts a distorted octahedral geometry.

Original language	English
Pages (from-to)	711-715
Number of pages	5
Journal	Polyhedron
Volume	11
Issue number	6
DOIs	https://doi.org/10.1016/S0277-5387(00)83330-6
State	Published - 1992

Bibliographical note

Funding Information:
Acknowledgements-We thank the National Science Foundation and the Robert A. Welch Foundation for generousfi nancial support.

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/S0277-5387(00)83330-6

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title = "A bis(pyrazolyl)borate complex of silicon(IV)",

abstract = "The first pyrazolylborate complex of silicon, [Ph2B(pz)2]2SiCl2, has been prepared via the reaction of K[Ph2B(pz)2] with SiCl4. The structure of this complex has been determined by X-ray crystallography. The bis(pyrazolyl)borate ligand behaves in a bidentate fashion and the silicon adopts a distorted octahedral geometry.",

author = "Atwood, {Vicki O.} and Atwood, {David A.} and Cowley, {Alan H.} and Swiatoslaw Trofimenko",

note = "Funding Information: Acknowledgements-We thank the National Science Foundation and the Robert A. Welch Foundation for generousfi nancial support.",

year = "1992",

doi = "10.1016/S0277-5387(00)83330-6",

language = "English",

volume = "11",

pages = "711--715",

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T1 - A bis(pyrazolyl)borate complex of silicon(IV)

AU - Atwood, Vicki O.

AU - Atwood, David A.

AU - Cowley, Alan H.

AU - Trofimenko, Swiatoslaw

N1 - Funding Information: Acknowledgements-We thank the National Science Foundation and the Robert A. Welch Foundation for generousfi nancial support.

PY - 1992

Y1 - 1992

N2 - The first pyrazolylborate complex of silicon, [Ph2B(pz)2]2SiCl2, has been prepared via the reaction of K[Ph2B(pz)2] with SiCl4. The structure of this complex has been determined by X-ray crystallography. The bis(pyrazolyl)borate ligand behaves in a bidentate fashion and the silicon adopts a distorted octahedral geometry.

AB - The first pyrazolylborate complex of silicon, [Ph2B(pz)2]2SiCl2, has been prepared via the reaction of K[Ph2B(pz)2] with SiCl4. The structure of this complex has been determined by X-ray crystallography. The bis(pyrazolyl)borate ligand behaves in a bidentate fashion and the silicon adopts a distorted octahedral geometry.

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JO - Polyhedron

JF - Polyhedron

IS - 6

ER -

A bis(pyrazolyl)borate complex of silicon(IV)

Abstract

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