A bis(pyrazolyl)borate complex of silicon(IV)

Vicki O. Atwood; David A. Atwood; Alan H. Cowley; Swiatoslaw Trofimenko

doi:10.1016/S0277-5387(00)83330-6

A bis(pyrazolyl)borate complex of silicon(IV)

Vicki O. Atwood
, David A. Atwood
, Alan H. Cowley
, Swiatoslaw Trofimenko

Research output: Contribution to journal › Article › peer-review

10 Scopus citations

Abstract

The first pyrazolylborate complex of silicon, [Ph₂B(pz)₂]₂SiCl₂, has been prepared via the reaction of K[Ph₂B(pz)₂] with SiCl₄. The structure of this complex has been determined by X-ray crystallography. The bis(pyrazolyl)borate ligand behaves in a bidentate fashion and the silicon adopts a distorted octahedral geometry.

Original language	English
Pages (from-to)	711-715
Number of pages	5
Journal	Polyhedron
Volume	11
Issue number	6
DOIs	https://doi.org/10.1016/S0277-5387(00)83330-6
State	Published - 1992

Bibliographical note

Funding Information:
Acknowledgements-We thank the National Science Foundation and the Robert A. Welch Foundation for generousfi nancial support.

Funding

Acknowledgements-We thank the National Science Foundation and the Robert A. Welch Foundation for generousfi nancial support.

Funders
Robert A. Welch Foundation
National Science Foundation (NSF)

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/S0277-5387(00)83330-6

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title = "A bis(pyrazolyl)borate complex of silicon(IV)",

abstract = "The first pyrazolylborate complex of silicon, [Ph2B(pz)2]2SiCl2, has been prepared via the reaction of K[Ph2B(pz)2] with SiCl4. The structure of this complex has been determined by X-ray crystallography. The bis(pyrazolyl)borate ligand behaves in a bidentate fashion and the silicon adopts a distorted octahedral geometry.",

author = "Atwood, \{Vicki O.\} and Atwood, \{David A.\} and Cowley, \{Alan H.\} and Swiatoslaw Trofimenko",

note = "Funding Information: Acknowledgements-We thank the National Science Foundation and the Robert A. Welch Foundation for generousfi nancial support.",

year = "1992",

doi = "10.1016/S0277-5387(00)83330-6",

language = "English",

volume = "11",

pages = "711--715",

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T1 - A bis(pyrazolyl)borate complex of silicon(IV)

AU - Atwood, Vicki O.

AU - Atwood, David A.

AU - Cowley, Alan H.

AU - Trofimenko, Swiatoslaw

N1 - Funding Information: Acknowledgements-We thank the National Science Foundation and the Robert A. Welch Foundation for generousfi nancial support.

PY - 1992

Y1 - 1992

N2 - The first pyrazolylborate complex of silicon, [Ph2B(pz)2]2SiCl2, has been prepared via the reaction of K[Ph2B(pz)2] with SiCl4. The structure of this complex has been determined by X-ray crystallography. The bis(pyrazolyl)borate ligand behaves in a bidentate fashion and the silicon adopts a distorted octahedral geometry.

AB - The first pyrazolylborate complex of silicon, [Ph2B(pz)2]2SiCl2, has been prepared via the reaction of K[Ph2B(pz)2] with SiCl4. The structure of this complex has been determined by X-ray crystallography. The bis(pyrazolyl)borate ligand behaves in a bidentate fashion and the silicon adopts a distorted octahedral geometry.

UR - https://www.scopus.com/pages/publications/0040053770

UR - https://www.scopus.com/pages/publications/0040053770#tab=citedBy

U2 - 10.1016/S0277-5387(00)83330-6

DO - 10.1016/S0277-5387(00)83330-6

M3 - Article

AN - SCOPUS:0040053770

SN - 0277-5387

VL - 11

SP - 711

EP - 715

JO - Polyhedron

JF - Polyhedron

IS - 6

ER -

A bis(pyrazolyl)borate complex of silicon(IV)

Abstract

Bibliographical note

Funding

ASJC Scopus subject areas

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