3-p-Tolyl-3-trifluoromethyldiazirine was studied by laser flash photolysis (LFP) to obtain the absolute kinetics of p-tolyl(trifluoromethyl)carbene 1. The absolute rate constants for the reactions of 1 with pyridine, ketones and quenchers of biological interest were obtained. The implications of the data for photoaffinity labeling experiments are discussed.
|Number of pages||7|
|Journal||Journal of the Chemical Society. Perkin Transactions 2|
|State||Published - May 1998|
ASJC Scopus subject areas
- Chemistry (all)