A laser flash photolysis study of p-tolyl(trifluoromethyl)carbene

Atnaf Admasu, Anna D. Gudmundsdóttir, Matthew S. Platz, David S. Watt, Stephan Kwiatkowski, Peter J. Crocker

Research output: Contribution to journalArticlepeer-review

36 Scopus citations

Abstract

3-p-Tolyl-3-trifluoromethyldiazirine was studied by laser flash photolysis (LFP) to obtain the absolute kinetics of p-tolyl(trifluoromethyl)carbene 1. The absolute rate constants for the reactions of 1 with pyridine, ketones and quenchers of biological interest were obtained. The implications of the data for photoaffinity labeling experiments are discussed.

Original languageEnglish
Pages (from-to)1093-1099
Number of pages7
JournalJournal of the Chemical Society. Perkin Transactions 2
Issue number5
DOIs
StatePublished - May 1998

ASJC Scopus subject areas

  • Chemistry (all)

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