A mixed-valence bis(diarylamino)stilbene: Crystal structure and comparison of electronic coupling with biphenyl and tolane analogues

Stephen Barlow; Chad Risko; Veaceslav Coropceanu; Neil M. Tucker; Simon C. Jones; Zerubba Levi; Viktor N. Khrustalev; Mikhail Yu Antipin; Tiffany L. Kinnibrugh; Tatiana Timofeeva; Seth R. Marder; Jean Luc Brédas

doi:10.1039/b415018j

A mixed-valence bis(diarylamino)stilbene: Crystal structure and comparison of electronic coupling with biphenyl and tolane analogues

Stephen Barlow, Chad Risko, Veaceslav Coropceanu, Neil M. Tucker, Simon C. Jones, Zerubba Levi, Viktor N. Khrustalev, Mikhail Yu Antipin, Tiffany L. Kinnibrugh, Tatiana Timofeeva, Seth R. Marder, Jean Luc Brédas

Chemistry

Research output: Contribution to journal › Article › peer-review

55 Scopus citations

Abstract

The E-4,4′-bis[di(p-anisyl)amino]stilbene cation is a class-III mixed-valence species with electronic coupling comparable to that in its biphenyl-bridged analogue, whereas its tolane-bridged analogue belongs to class II.

Original language	English
Pages (from-to)	764-766
Number of pages	3
Journal	Chemical Communications
Issue number	6
DOIs	https://doi.org/10.1039/b415018j
State	Published - Feb 14 2005

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry (all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/b415018j

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Barlow, S., Risko, C., Coropceanu, V., Tucker, N. M., Jones, S. C., Levi, Z., Khrustalev, V. N., Antipin, M. Y., Kinnibrugh, T. L., Timofeeva, T., Marder, S. R., & Brédas, J. L. (2005). A mixed-valence bis(diarylamino)stilbene: Crystal structure and comparison of electronic coupling with biphenyl and tolane analogues. Chemical Communications, (6), 764-766. https://doi.org/10.1039/b415018j

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abstract = "The E-4,4′-bis[di(p-anisyl)amino]stilbene cation is a class-III mixed-valence species with electronic coupling comparable to that in its biphenyl-bridged analogue, whereas its tolane-bridged analogue belongs to class II.",

author = "Stephen Barlow and Chad Risko and Veaceslav Coropceanu and Tucker, {Neil M.} and Jones, {Simon C.} and Zerubba Levi and Khrustalev, {Viktor N.} and Antipin, {Mikhail Yu} and Kinnibrugh, {Tiffany L.} and Tatiana Timofeeva and Marder, {Seth R.} and Br{\'e}das, {Jean Luc}",

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doi = "10.1039/b415018j",

language = "English",

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Barlow, S, Risko, C, Coropceanu, V, Tucker, NM, Jones, SC, Levi, Z, Khrustalev, VN, Antipin, MY, Kinnibrugh, TL, Timofeeva, T, Marder, SR & Brédas, JL 2005, 'A mixed-valence bis(diarylamino)stilbene: Crystal structure and comparison of electronic coupling with biphenyl and tolane analogues', Chemical Communications, no. 6, pp. 764-766. https://doi.org/10.1039/b415018j

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T1 - A mixed-valence bis(diarylamino)stilbene

T2 - Crystal structure and comparison of electronic coupling with biphenyl and tolane analogues

AU - Barlow, Stephen

AU - Risko, Chad

AU - Coropceanu, Veaceslav

AU - Tucker, Neil M.

AU - Jones, Simon C.

AU - Levi, Zerubba

AU - Khrustalev, Viktor N.

AU - Antipin, Mikhail Yu

AU - Kinnibrugh, Tiffany L.

AU - Timofeeva, Tatiana

AU - Marder, Seth R.

AU - Brédas, Jean Luc

PY - 2005/2/14

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AB - The E-4,4′-bis[di(p-anisyl)amino]stilbene cation is a class-III mixed-valence species with electronic coupling comparable to that in its biphenyl-bridged analogue, whereas its tolane-bridged analogue belongs to class II.

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JF - Chemical Communications

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A mixed-valence bis(diarylamino)stilbene: Crystal structure and comparison of electronic coupling with biphenyl and tolane analogues

Abstract

ASJC Scopus subject areas

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