A Novel Mitigation Mechanism for Photo-Induced Trapping in an Anthradithiophene Derivative Using Additives

Iyad Nasrallah; Mahesh Kumar Ravva; Katharina Broch; Jiri Novak; John Armitage; Guillaume Schweicher; Aditya Sadhanala; John E. Anthony; Jean Luc Bredas; Henning Sirringhaus

doi:10.1002/aelm.202000250

A Novel Mitigation Mechanism for Photo-Induced Trapping in an Anthradithiophene Derivative Using Additives

Iyad Nasrallah
, Mahesh Kumar Ravva
, Katharina Broch
, Jiri Novak
, John Armitage
, Guillaume Schweicher
, Aditya Sadhanala
, John E. Anthony
, Jean Luc Bredas
, Henning Sirringhaus

Research output: Contribution to journal › Article › peer-review

7 Scopus citations

Abstract

A novel trap mitigation mechanism using molecular additives, which relieves a characteristic early turn-on voltage in a high-mobility p-type acene-based small-molecule organic semiconductor, when processed from hydrous solvents, is reported. The early turn-on voltage is attributed to photo-induced trapping, and additive incorporation is found to be very effective in suppressing this effect. Remarkably, the molecular additive does not disturb the charge transport properties of the small-molecule semiconductor, but rather intercalates in the crystal structure. This novel technique allows for the solution-processing of small molecular semiconductors from hydrous solvents, greatly simplifying manufacturing processes for large-area electronics. Along with various electric and spectroscopic characterization techniques, simulations have given a deeper insight into the trap mitigation effect induced by the additive.

Original language	English
Article number	2000250
Journal	Advanced Electronic Materials
Volume	6
Issue number	9
DOIs	https://doi.org/10.1002/aelm.202000250
State	Published - Sep 1 2020

Bibliographical note

Publisher Copyright:
© 2020 Wiley-VCH GmbH

Funding

I.N. acknowledges the financial support from FlexEnable Ltd., as well as the EPSRC Centre for Innovative Manufacturing in Large-Area Electronics (CIMLAE, EP/K03099X/1). G.S. acknowledges postdoctoral fellowship support from the Wiener-Anspach Foundation and The Leverhulme Trust (Early Career Fellowship supported by the Isaac Newton Trust). J.N. acknowledges support from MEYS Czech Republic, project CEITEC 2020 (Grant No. LQ1601). I.N. acknowledges the financial support from FlexEnable Ltd., as well as the EPSRC Centre for Innovative Manufacturing in Large‐Area Electronics (CIMLAE, EP/K03099X/1). G.S. acknowledges postdoctoral fellowship support from the Wiener‐Anspach Foundation and The Leverhulme Trust (Early Career Fellowship supported by the Isaac Newton Trust). J.N. acknowledges support from MEYS Czech Republic, project CEITEC 2020 (Grant No. LQ1601).

Funders	Funder number
CIMLAE	EP/K03099X/1
EPSRC Centre for Innovative Manufacturing in Large‐Area Electronics
FlexEnable Ltd.
Wiener-Anspach Foundation
Wiener-Anspach Foundation
Leverhulme Trust
Innovative electronics Manufacturing Research Centre
Ministerstvo Školství, Mládeže a Tělovýchovy	LQ1601
Isaac Newton Trust

Keywords

electron trapping
light stability
operational stability
organic field-effect transistors
organic semiconductors

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials

Access to Document

10.1002/aelm.202000250

Cite this

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title = "A Novel Mitigation Mechanism for Photo-Induced Trapping in an Anthradithiophene Derivative Using Additives",

abstract = "A novel trap mitigation mechanism using molecular additives, which relieves a characteristic early turn-on voltage in a high-mobility p-type acene-based small-molecule organic semiconductor, when processed from hydrous solvents, is reported. The early turn-on voltage is attributed to photo-induced trapping, and additive incorporation is found to be very effective in suppressing this effect. Remarkably, the molecular additive does not disturb the charge transport properties of the small-molecule semiconductor, but rather intercalates in the crystal structure. This novel technique allows for the solution-processing of small molecular semiconductors from hydrous solvents, greatly simplifying manufacturing processes for large-area electronics. Along with various electric and spectroscopic characterization techniques, simulations have given a deeper insight into the trap mitigation effect induced by the additive.",

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author = "Iyad Nasrallah and Ravva, \{Mahesh Kumar\} and Katharina Broch and Jiri Novak and John Armitage and Guillaume Schweicher and Aditya Sadhanala and Anthony, \{John E.\} and Bredas, \{Jean Luc\} and Henning Sirringhaus",

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doi = "10.1002/aelm.202000250",

language = "English",

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AU - Nasrallah, Iyad

AU - Ravva, Mahesh Kumar

AU - Broch, Katharina

AU - Novak, Jiri

AU - Armitage, John

AU - Schweicher, Guillaume

AU - Sadhanala, Aditya

AU - Anthony, John E.

AU - Bredas, Jean Luc

AU - Sirringhaus, Henning

PY - 2020/9/1

Y1 - 2020/9/1

N2 - A novel trap mitigation mechanism using molecular additives, which relieves a characteristic early turn-on voltage in a high-mobility p-type acene-based small-molecule organic semiconductor, when processed from hydrous solvents, is reported. The early turn-on voltage is attributed to photo-induced trapping, and additive incorporation is found to be very effective in suppressing this effect. Remarkably, the molecular additive does not disturb the charge transport properties of the small-molecule semiconductor, but rather intercalates in the crystal structure. This novel technique allows for the solution-processing of small molecular semiconductors from hydrous solvents, greatly simplifying manufacturing processes for large-area electronics. Along with various electric and spectroscopic characterization techniques, simulations have given a deeper insight into the trap mitigation effect induced by the additive.

AB - A novel trap mitigation mechanism using molecular additives, which relieves a characteristic early turn-on voltage in a high-mobility p-type acene-based small-molecule organic semiconductor, when processed from hydrous solvents, is reported. The early turn-on voltage is attributed to photo-induced trapping, and additive incorporation is found to be very effective in suppressing this effect. Remarkably, the molecular additive does not disturb the charge transport properties of the small-molecule semiconductor, but rather intercalates in the crystal structure. This novel technique allows for the solution-processing of small molecular semiconductors from hydrous solvents, greatly simplifying manufacturing processes for large-area electronics. Along with various electric and spectroscopic characterization techniques, simulations have given a deeper insight into the trap mitigation effect induced by the additive.

KW - electron trapping

KW - light stability

KW - operational stability

KW - organic field-effect transistors

KW - organic semiconductors

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A Novel Mitigation Mechanism for Photo-Induced Trapping in an Anthradithiophene Derivative Using Additives

Abstract

Bibliographical note

Funding

Keywords

ASJC Scopus subject areas

Access to Document

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