A Novel Type of Ring Contraction as Non‐Enzymatic Step in the Later Stages of the Biosynthesis of Urdamycin H

Jürgen Rohr

doi:10.1002/anie.199010511

A Novel Type of Ring Contraction as Non‐Enzymatic Step in the Later Stages of the Biosynthesis of Urdamycin H

Jürgen Rohr

Pharmaceutical Sciences

Research output: Contribution to journal › Article › peer-review

13 Scopus citations

Abstract

Intramolecular ring closure and oxidative decarboxylation following lactone ring opening allow urdamycin H (2) to be synthesized from urdamycin C (1) in a nonenzymatic process. This was the result of biosynthetic studies and model reactions on the urdamycin system. (Figure Presented.)

Original language	English
Pages (from-to)	1051-1053
Number of pages	3
Journal	Angewandte Chemie International Edition in English
Volume	29
Issue number	9
DOIs	https://doi.org/10.1002/anie.199010511
State	Published - Sep 1990

ASJC Scopus subject areas

Catalysis
General Chemistry

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10.1002/anie.199010511

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title = "A Novel Type of Ring Contraction as Non‐Enzymatic Step in the Later Stages of the Biosynthesis of Urdamycin H",

abstract = "Intramolecular ring closure and oxidative decarboxylation following lactone ring opening allow urdamycin H (2) to be synthesized from urdamycin C (1) in a nonenzymatic process. This was the result of biosynthetic studies and model reactions on the urdamycin system. (Figure Presented.)",

author = "J{\"u}rgen Rohr",

year = "1990",

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doi = "10.1002/anie.199010511",

language = "English",

volume = "29",

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N2 - Intramolecular ring closure and oxidative decarboxylation following lactone ring opening allow urdamycin H (2) to be synthesized from urdamycin C (1) in a nonenzymatic process. This was the result of biosynthetic studies and model reactions on the urdamycin system. (Figure Presented.)

AB - Intramolecular ring closure and oxidative decarboxylation following lactone ring opening allow urdamycin H (2) to be synthesized from urdamycin C (1) in a nonenzymatic process. This was the result of biosynthetic studies and model reactions on the urdamycin system. (Figure Presented.)

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ER -

A Novel Type of Ring Contraction as Non‐Enzymatic Step in the Later Stages of the Biosynthesis of Urdamycin H

Abstract

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