TY - JOUR
T1 - Activation of small molecules by transition metal cluster compounds. Oxidative cleavage of a metal-metal bond by HCl in an osmium cluster compound
AU - Adams, Richard D.
AU - Golembeski, Nancy M.
AU - Selegue, John P.
PY - 1980
Y1 - 1980
N2 - The complex (μ3-S)(μ3-n2-SCH2)Os3(CO)8[P(CH3)2C6H5] reacts with HCl in an addition process to form the molecule (μ3-S)(μ3-n2-SCH2)(H)Os3(CO)8[P(CH3)2C6H5]Cl. The product was characterized by IR, 1H NMR and x-ray crystallographic methods. The structural analysis shows that the HCl addition has caused a cleavage of one of the metal-metal bonds.
AB - The complex (μ3-S)(μ3-n2-SCH2)Os3(CO)8[P(CH3)2C6H5] reacts with HCl in an addition process to form the molecule (μ3-S)(μ3-n2-SCH2)(H)Os3(CO)8[P(CH3)2C6H5]Cl. The product was characterized by IR, 1H NMR and x-ray crystallographic methods. The structural analysis shows that the HCl addition has caused a cleavage of one of the metal-metal bonds.
UR - http://www.scopus.com/inward/record.url?scp=85025749349&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=85025749349&partnerID=8YFLogxK
U2 - 10.1016/S0022-328X(00)86086-6
DO - 10.1016/S0022-328X(00)86086-6
M3 - Article
AN - SCOPUS:85025749349
SN - 0022-328X
VL - 193
SP - C7-C12
JO - Journal of Organometallic Chemistry
JF - Journal of Organometallic Chemistry
IS - 1
ER -