Alkyl-alkenyl cross coupling via alkyl cobaloxime radical chemistry.An alkyl equivalent to the heck reaction compatible with common organic functional groups

Bruce P. Branchaud; Mark S. Meier; Youngshin Choi

doi:10.1016/S0040-4039(00)80043-X

Alkyl-alkenyl cross coupling via alkyl cobaloxime radical chemistry.An alkyl equivalent to the heck reaction compatible with common organic functional groups

Bruce P. Branchaud, Mark S. Meier, Youngshin Choi

Research output: Contribution to journal › Article › peer-review

77 Scopus citations

Abstract

A novel cobalt-mediated radical-olefin coupling reaction is described which regenerates the olefin functionality in the final product. The regeneration of olefin functionality is unique among radical-olefin couplings using simple activated alkenes.

Original language	English
Pages (from-to)	167-170
Number of pages	4
Journal	Tetrahedron Letters
Volume	29
Issue number	2
DOIs	https://doi.org/10.1016/S0040-4039(00)80043-X
State	Published - 1988

Bibliographical note

Funding Information:
Acknowledgements. We acknowledge the financial assistance of the University of Oregon, NIH BRS 2 SO7 RR07080, an M. J. Murdoch Charitable Trust Grant of the Research Corporation, and the donors of the Petroleum Research Fund, administered by the America1 Chemical Society. The General Electric BE-300 NMR spectrometer used in this work was purchased with funds provided by PHS RR 02336 and NSF CHE 9411177.

ASJC Scopus subject areas

Biochemistry
Drug Discovery
Organic Chemistry

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10.1016/S0040-4039(00)80043-X

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title = "Alkyl-alkenyl cross coupling via alkyl cobaloxime radical chemistry.An alkyl equivalent to the heck reaction compatible with common organic functional groups",

abstract = "A novel cobalt-mediated radical-olefin coupling reaction is described which regenerates the olefin functionality in the final product. The regeneration of olefin functionality is unique among radical-olefin couplings using simple activated alkenes.",

author = "Branchaud, {Bruce P.} and Meier, {Mark S.} and Youngshin Choi",

note = "Funding Information: Acknowledgements. We acknowledge the financial assistance of the University of Oregon, NIH BRS 2 SO7 RR07080, an M. J. Murdoch Charitable Trust Grant of the Research Corporation, and the donors of the Petroleum Research Fund, administered by the America1 Chemical Society. The General Electric BE-300 NMR spectrometer used in this work was purchased with funds provided by PHS RR 02336 and NSF CHE 9411177.",

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doi = "10.1016/S0040-4039(00)80043-X",

language = "English",

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T1 - Alkyl-alkenyl cross coupling via alkyl cobaloxime radical chemistry.An alkyl equivalent to the heck reaction compatible with common organic functional groups

AU - Branchaud, Bruce P.

AU - Meier, Mark S.

AU - Choi, Youngshin

N1 - Funding Information: Acknowledgements. We acknowledge the financial assistance of the University of Oregon, NIH BRS 2 SO7 RR07080, an M. J. Murdoch Charitable Trust Grant of the Research Corporation, and the donors of the Petroleum Research Fund, administered by the America1 Chemical Society. The General Electric BE-300 NMR spectrometer used in this work was purchased with funds provided by PHS RR 02336 and NSF CHE 9411177.

PY - 1988

Y1 - 1988

N2 - A novel cobalt-mediated radical-olefin coupling reaction is described which regenerates the olefin functionality in the final product. The regeneration of olefin functionality is unique among radical-olefin couplings using simple activated alkenes.

AB - A novel cobalt-mediated radical-olefin coupling reaction is described which regenerates the olefin functionality in the final product. The regeneration of olefin functionality is unique among radical-olefin couplings using simple activated alkenes.

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U2 - 10.1016/S0040-4039(00)80043-X

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Alkyl-alkenyl cross coupling via alkyl cobaloxime radical chemistry.An alkyl equivalent to the heck reaction compatible with common organic functional groups

Abstract

Bibliographical note

ASJC Scopus subject areas

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