(Alkylamido)gallate Complexes of the Group 1 and 2 Elements

David A. Atwood; Alan H. Cowley; Richard A. Jones

doi:10.1021/om00025a040

(Alkylamido)gallate Complexes of the Group 1 and 2 Elements

David A. Atwood, Alan H. Cowley, Richard A. Jones

Chemistry

Research output: Contribution to journal › Comment/debate

14 Scopus citations

Abstract

The reaction of 2 equiv of LiNH(t-Bu) with [Cy₂GaCl]₂ (Cy = cyclohexyl) produces the gallate complex Li(THF)₂(μ-NH(t-Bu))₂GaCy₂ (1). The reaction of 2 equiv of Li(3,5-Me₂Pz) (Pz = pyrazolyl) with [Cy₂GaCl]₂ produces the gallate species MgCl(THF)₂(μ-3,5-Me₂Pz)₂GaCy₂(2). An X-ray structural study shows that the amide ligands for 1 and 2 bridge from the Ga atom to Li⁺ and MgCl⁺, respectively.

Original language	English
Pages (from-to)	236-238
Number of pages	3
Journal	Organometallics
Volume	12
Issue number	1
DOIs	https://doi.org/10.1021/om00025a040
State	Published - 1993

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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@article{0261cfb972fb49dc8eb6eaecd9d73111,

title = "(Alkylamido)gallate Complexes of the Group 1 and 2 Elements",

abstract = "The reaction of 2 equiv of LiNH(t-Bu) with [Cy2GaCl]2 (Cy = cyclohexyl) produces the gallate complex Li(THF)2(μ-NH(t-Bu))2GaCy2 (1). The reaction of 2 equiv of Li(3,5-Me2Pz) (Pz = pyrazolyl) with [Cy2GaCl]2 produces the gallate species MgCl(THF)2(μ-3,5-Me2Pz)2GaCy2(2). An X-ray structural study shows that the amide ligands for 1 and 2 bridge from the Ga atom to Li+ and MgCl+, respectively.",

author = "Atwood, {David A.} and Cowley, {Alan H.} and Jones, {Richard A.}",

year = "1993",

doi = "10.1021/om00025a040",

language = "English",

volume = "12",

pages = "236--238",

number = "1",

}

TY - JOUR

T1 - (Alkylamido)gallate Complexes of the Group 1 and 2 Elements

AU - Atwood, David A.

AU - Cowley, Alan H.

AU - Jones, Richard A.

PY - 1993

Y1 - 1993

N2 - The reaction of 2 equiv of LiNH(t-Bu) with [Cy2GaCl]2 (Cy = cyclohexyl) produces the gallate complex Li(THF)2(μ-NH(t-Bu))2GaCy2 (1). The reaction of 2 equiv of Li(3,5-Me2Pz) (Pz = pyrazolyl) with [Cy2GaCl]2 produces the gallate species MgCl(THF)2(μ-3,5-Me2Pz)2GaCy2(2). An X-ray structural study shows that the amide ligands for 1 and 2 bridge from the Ga atom to Li+ and MgCl+, respectively.

AB - The reaction of 2 equiv of LiNH(t-Bu) with [Cy2GaCl]2 (Cy = cyclohexyl) produces the gallate complex Li(THF)2(μ-NH(t-Bu))2GaCy2 (1). The reaction of 2 equiv of Li(3,5-Me2Pz) (Pz = pyrazolyl) with [Cy2GaCl]2 produces the gallate species MgCl(THF)2(μ-3,5-Me2Pz)2GaCy2(2). An X-ray structural study shows that the amide ligands for 1 and 2 bridge from the Ga atom to Li+ and MgCl+, respectively.

UR - http://www.scopus.com/inward/record.url?scp=0000298947&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0000298947&partnerID=8YFLogxK

U2 - 10.1021/om00025a040

DO - 10.1021/om00025a040

M3 - Comment/debate

AN - SCOPUS:0000298947

SN - 0276-7333

VL - 12

SP - 236

EP - 238

JO - Organometallics

JF - Organometallics

IS - 1

ER -

(Alkylamido)gallate Complexes of the Group 1 and 2 Elements

Abstract

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