An approach to the carbocyclic skeleton of shinjudilactone using a benzilic acid rearrangement

Norma K. Dunlap; Raymond S. Gross; David S. Watt

doi:10.1080/00397918808057814

An approach to the carbocyclic skeleton of shinjudilactone using a benzilic acid rearrangement

Norma K. Dunlap, Raymond S. Gross, David S. Watt

Molecular and Cellular Biochemistry

Research output: Contribution to journal › Article › peer-review

4 Scopus citations

Abstract

A benzilic acid rearrangement of a substituted 19-nor-7a,12a-epoxy-12β-hydroxy-9β-podocarpan-11-one led to a ring contraction in the C ring to furnish the carbocyclic skeleton of the quassinoid, shinjudilactone.

Original language	English
Pages (from-to)	13-20
Number of pages	8
Journal	Synthetic Communications
Volume	18
Issue number	1
DOIs	https://doi.org/10.1080/00397918808057814
State	Published - Jan 1 1988

ASJC Scopus subject areas

Organic Chemistry

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title = "An approach to the carbocyclic skeleton of shinjudilactone using a benzilic acid rearrangement",

abstract = "A benzilic acid rearrangement of a substituted 19-nor-7a,12a-epoxy-12β-hydroxy-9β-podocarpan-11-one led to a ring contraction in the C ring to furnish the carbocyclic skeleton of the quassinoid, shinjudilactone.",

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AU - Gross, Raymond S.

AU - Watt, David S.

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N2 - A benzilic acid rearrangement of a substituted 19-nor-7a,12a-epoxy-12β-hydroxy-9β-podocarpan-11-one led to a ring contraction in the C ring to furnish the carbocyclic skeleton of the quassinoid, shinjudilactone.

AB - A benzilic acid rearrangement of a substituted 19-nor-7a,12a-epoxy-12β-hydroxy-9β-podocarpan-11-one led to a ring contraction in the C ring to furnish the carbocyclic skeleton of the quassinoid, shinjudilactone.

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An approach to the carbocyclic skeleton of shinjudilactone using a benzilic acid rearrangement

Abstract

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