An efficient butenolide annulation via α'-chloroacetoxylation of enones using manganese(III) acetate and chloroacetic acid

A. S. Demir, H. Akgun, C. Tanyeli, T. Sayrac, D. S. Watt

Research output: Contribution to journalArticlepeer-review

15 Scopus citations

Abstract

The α'-chloroacetoxylation of α,β-unsaturated ketones using manganese(III) acetate and chloroacetic acid followed by Arbuzov reaction and intramolecular Horner-Emmons olefination provided a convenient synthesis of annulated 2-buten-4-olides.

Original languageEnglish
Pages (from-to)719-721
Number of pages3
JournalSynthesis
Issue number9
DOIs
StatePublished - 1991

ASJC Scopus subject areas

  • Catalysis
  • Organic Chemistry

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