An indium-phosphorus heterocubane as a new type of indium phosphide precursor

David A. Atwood; Alan H. Cowley; Richard A. Jones; Miguel A. Mardones

doi:10.1016/0022-328X(93)80126-V

An indium-phosphorus heterocubane as a new type of indium phosphide precursor

David A. Atwood, Alan H. Cowley, Richard A. Jones, Miguel A. Mardones

Research output: Contribution to journal › Article › peer-review

38 Scopus citations

Abstract

The first indium-phosphorus cubane, [ⁱPrIn(μ₃-PSiPh₃)]₄ (1) has been prepared via the reaction of Li₂[PSiPh₃] with ⁱPrInI₂. The structure of 1 has been determined by X-ray analysis: monoclinic, space group P2₁/c with a = 15.611(3), b = 25.767(2), c = 22.541(6) Å, β = 96.19(2)°, and Z = 4. Polycrystalline films of indium phosphide have been grown on Si(100) wafers from 1 in a horizontal hot-wall reactor at 500°C. Compound 1 is unstable with respect to photolysis and electrochemical oxidation; however it is relatively stable toward alcoholysis.

Original language	English
Pages (from-to)	C1
Journal	Journal of Organometallic Chemistry
Volume	449
Issue number	1-2
DOIs	https://doi.org/10.1016/0022-328X(93)80126-V
State	Published - May 4 1993

Bibliographical note

Funding Information:
We thank the National Science Foundation (Grant CHE 9108228a) nd the Robert A. Welch Foundation for generousf inancial support.

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

Access to Document

10.1016/0022-328X(93)80126-V

Cite this

@article{66824433464f4bf7a3522fa1f8c84a58,

title = "An indium-phosphorus heterocubane as a new type of indium phosphide precursor",

abstract = "The first indium-phosphorus cubane, [iPrIn(μ3-PSiPh3)]4 (1) has been prepared via the reaction of Li2[PSiPh3] with iPrInI2. The structure of 1 has been determined by X-ray analysis: monoclinic, space group P21/c with a = 15.611(3), b = 25.767(2), c = 22.541(6) {\AA}, β = 96.19(2)°, and Z = 4. Polycrystalline films of indium phosphide have been grown on Si(100) wafers from 1 in a horizontal hot-wall reactor at 500°C. Compound 1 is unstable with respect to photolysis and electrochemical oxidation; however it is relatively stable toward alcoholysis.",

author = "Atwood, {David A.} and Cowley, {Alan H.} and Jones, {Richard A.} and Mardones, {Miguel A.}",

year = "1993",

month = may,

day = "4",

doi = "10.1016/0022-328X(93)80126-V",

language = "English",

volume = "449",

pages = "C1",

number = "1-2",

}

TY - JOUR

T1 - An indium-phosphorus heterocubane as a new type of indium phosphide precursor

AU - Atwood, David A.

AU - Cowley, Alan H.

AU - Jones, Richard A.

AU - Mardones, Miguel A.

PY - 1993/5/4

Y1 - 1993/5/4

N2 - The first indium-phosphorus cubane, [iPrIn(μ3-PSiPh3)]4 (1) has been prepared via the reaction of Li2[PSiPh3] with iPrInI2. The structure of 1 has been determined by X-ray analysis: monoclinic, space group P21/c with a = 15.611(3), b = 25.767(2), c = 22.541(6) Å, β = 96.19(2)°, and Z = 4. Polycrystalline films of indium phosphide have been grown on Si(100) wafers from 1 in a horizontal hot-wall reactor at 500°C. Compound 1 is unstable with respect to photolysis and electrochemical oxidation; however it is relatively stable toward alcoholysis.

AB - The first indium-phosphorus cubane, [iPrIn(μ3-PSiPh3)]4 (1) has been prepared via the reaction of Li2[PSiPh3] with iPrInI2. The structure of 1 has been determined by X-ray analysis: monoclinic, space group P21/c with a = 15.611(3), b = 25.767(2), c = 22.541(6) Å, β = 96.19(2)°, and Z = 4. Polycrystalline films of indium phosphide have been grown on Si(100) wafers from 1 in a horizontal hot-wall reactor at 500°C. Compound 1 is unstable with respect to photolysis and electrochemical oxidation; however it is relatively stable toward alcoholysis.

UR - http://www.scopus.com/inward/record.url?scp=0001823081&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0001823081&partnerID=8YFLogxK

U2 - 10.1016/0022-328X(93)80126-V

DO - 10.1016/0022-328X(93)80126-V

M3 - Article

AN - SCOPUS:0001823081

SN - 0022-328X

VL - 449

SP - C1

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 1-2

ER -

An indium-phosphorus heterocubane as a new type of indium phosphide precursor

Abstract

Bibliographical note

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this