An indium-phosphorus heterocubane as a new type of indium phosphide precursor

David A. Atwood; Alan H. Cowley; Richard A. Jones; Miguel A. Mardones

doi:10.1016/0022-328X(93)80126-V

An indium-phosphorus heterocubane as a new type of indium phosphide precursor

David A. Atwood, Alan H. Cowley, Richard A. Jones, Miguel A. Mardones

Research output: Contribution to journal › Article › peer-review

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Abstract

The first indium-phosphorus cubane, [ⁱPrIn(μ₃-PSiPh₃)]₄ (1) has been prepared via the reaction of Li₂[PSiPh₃] with ⁱPrInI₂. The structure of 1 has been determined by X-ray analysis: monoclinic, space group P2₁/c with a = 15.611(3), b = 25.767(2), c = 22.541(6) Å, β = 96.19(2)°, and Z = 4. Polycrystalline films of indium phosphide have been grown on Si(100) wafers from 1 in a horizontal hot-wall reactor at 500°C. Compound 1 is unstable with respect to photolysis and electrochemical oxidation; however it is relatively stable toward alcoholysis.

Original language	English
Pages (from-to)	C1
Journal	Journal of Organometallic Chemistry
Volume	449
Issue number	1-2
DOIs	https://doi.org/10.1016/0022-328X(93)80126-V
State	Published - May 4 1993

Bibliographical note

Funding Information:
We thank the National Science Foundation (Grant CHE 9108228a) nd the Robert A. Welch Foundation for generousf inancial support.

Funding

We thank the National Science Foundation (Grant CHE 9108228a) nd the Robert A. Welch Foundation for generousf inancial support.

Funders	Funder number
Robert A. Welch Foundation
National Science Foundation (NSF)	CHE 9108228a

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/0022-328X(93)80126-V

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title = "An indium-phosphorus heterocubane as a new type of indium phosphide precursor",

abstract = "The first indium-phosphorus cubane, [iPrIn(μ3-PSiPh3)]4 (1) has been prepared via the reaction of Li2[PSiPh3] with iPrInI2. The structure of 1 has been determined by X-ray analysis: monoclinic, space group P21/c with a = 15.611(3), b = 25.767(2), c = 22.541(6) {\AA}, β = 96.19(2)°, and Z = 4. Polycrystalline films of indium phosphide have been grown on Si(100) wafers from 1 in a horizontal hot-wall reactor at 500°C. Compound 1 is unstable with respect to photolysis and electrochemical oxidation; however it is relatively stable toward alcoholysis.",

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AU - Atwood, David A.

AU - Cowley, Alan H.

AU - Jones, Richard A.

AU - Mardones, Miguel A.

PY - 1993/5/4

Y1 - 1993/5/4

N2 - The first indium-phosphorus cubane, [iPrIn(μ3-PSiPh3)]4 (1) has been prepared via the reaction of Li2[PSiPh3] with iPrInI2. The structure of 1 has been determined by X-ray analysis: monoclinic, space group P21/c with a = 15.611(3), b = 25.767(2), c = 22.541(6) Å, β = 96.19(2)°, and Z = 4. Polycrystalline films of indium phosphide have been grown on Si(100) wafers from 1 in a horizontal hot-wall reactor at 500°C. Compound 1 is unstable with respect to photolysis and electrochemical oxidation; however it is relatively stable toward alcoholysis.

AB - The first indium-phosphorus cubane, [iPrIn(μ3-PSiPh3)]4 (1) has been prepared via the reaction of Li2[PSiPh3] with iPrInI2. The structure of 1 has been determined by X-ray analysis: monoclinic, space group P21/c with a = 15.611(3), b = 25.767(2), c = 22.541(6) Å, β = 96.19(2)°, and Z = 4. Polycrystalline films of indium phosphide have been grown on Si(100) wafers from 1 in a horizontal hot-wall reactor at 500°C. Compound 1 is unstable with respect to photolysis and electrochemical oxidation; however it is relatively stable toward alcoholysis.

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An indium-phosphorus heterocubane as a new type of indium phosphide precursor

Abstract

Bibliographical note

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