An S = 6 cyanide-bridged octanuclear FeIII4Ni II4 complex that exhibits slow relaxation of the magnetization

Dongfeng Li; Sean Parkin; Guangbin Wang; Gordon T. Yee; Rodolphe Clérac; Wolfgang Wernsdorfer; Stephen M. Holmes

doi:10.1021/ja058626i

An S = 6 cyanide-bridged octanuclear Fe^III₄Ni ^II₄ complex that exhibits slow relaxation of the magnetization

Dongfeng Li, Sean Parkin, Guangbin Wang, Gordon T. Yee, Rodolphe Clérac, Wolfgang Wernsdorfer, Stephen M. Holmes

Chemistry

Research output: Contribution to journal › Article › peer-review

229 Scopus citations

Abstract

The synthesis and structural and magnetic characterization of an S = 6 cyanide-bridged octanuclear Fe^III₄Ni^II₄ (1) complex is described. Ac susceptibility and μ-SQUID measurements suggest that fast magnetization relaxation is present in zero-field due to quantum tunneling of the ground spin state (QTM) while application of small magnetic fields induces slow relaxation of the magnetization.

Original language	English
Pages (from-to)	4214-4215
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	128
Issue number	13
DOIs	https://doi.org/10.1021/ja058626i
State	Published - Apr 5 2006

ASJC Scopus subject areas

Catalysis
General Chemistry
Biochemistry
Colloid and Surface Chemistry

Access to Document

10.1021/ja058626i

Cite this

@article{03be104c7bd24ae9b07ca43d45bf8d7c,

title = "An S = 6 cyanide-bridged octanuclear FeIII4Ni II4 complex that exhibits slow relaxation of the magnetization",

abstract = "The synthesis and structural and magnetic characterization of an S = 6 cyanide-bridged octanuclear FeIII4NiII4 (1) complex is described. Ac susceptibility and μ-SQUID measurements suggest that fast magnetization relaxation is present in zero-field due to quantum tunneling of the ground spin state (QTM) while application of small magnetic fields induces slow relaxation of the magnetization.",

author = "Dongfeng Li and Sean Parkin and Guangbin Wang and Yee, {Gordon T.} and Rodolphe Cl{\'e}rac and Wolfgang Wernsdorfer and Holmes, {Stephen M.}",

year = "2006",

month = apr,

day = "5",

doi = "10.1021/ja058626i",

language = "English",

volume = "128",

pages = "4214--4215",

number = "13",

}

TY - JOUR

T1 - An S = 6 cyanide-bridged octanuclear FeIII4Ni II4 complex that exhibits slow relaxation of the magnetization

AU - Li, Dongfeng

AU - Parkin, Sean

AU - Wang, Guangbin

AU - Yee, Gordon T.

AU - Clérac, Rodolphe

AU - Wernsdorfer, Wolfgang

AU - Holmes, Stephen M.

PY - 2006/4/5

Y1 - 2006/4/5

N2 - The synthesis and structural and magnetic characterization of an S = 6 cyanide-bridged octanuclear FeIII4NiII4 (1) complex is described. Ac susceptibility and μ-SQUID measurements suggest that fast magnetization relaxation is present in zero-field due to quantum tunneling of the ground spin state (QTM) while application of small magnetic fields induces slow relaxation of the magnetization.

AB - The synthesis and structural and magnetic characterization of an S = 6 cyanide-bridged octanuclear FeIII4NiII4 (1) complex is described. Ac susceptibility and μ-SQUID measurements suggest that fast magnetization relaxation is present in zero-field due to quantum tunneling of the ground spin state (QTM) while application of small magnetic fields induces slow relaxation of the magnetization.

UR - http://www.scopus.com/inward/record.url?scp=33645471107&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=33645471107&partnerID=8YFLogxK

U2 - 10.1021/ja058626i

DO - 10.1021/ja058626i

M3 - Article

C2 - 16568981

AN - SCOPUS:33645471107

SN - 0002-7863

VL - 128

SP - 4214

EP - 4215

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 13

ER -

An S = 6 cyanide-bridged octanuclear Fe^III₄Ni ^II₄ complex that exhibits slow relaxation of the magnetization

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this