An unusual imine (N=C) alkylalumination reaction

Pingrong Wei; David Atwood

doi:10.1039/a701185g

An unusual imine (N=C) alkylalumination reaction

Pingrong Wei, David Atwood

Research output: Contribution to journal › Article › peer-review

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Abstract

Addition of 3 equiv. of AlMe₃ to a heptadentate Schiff-base ligand made from salicylaldehyde and bis(2-aminoethyl)-ethylenediamine (H₃L¹) results in an unusual alkylalumination of one of the imine bonds; addition of 2 equiv. of B(OMe)₃ or AlMe₃ to one of these ligands leads to the formation of bimetallic derivatives containing four- and five-coordinate metals, respectively.

Original language	English
Pages (from-to)	1427-1428
Number of pages	2
Journal	Chemical Communications
Issue number	15
DOIs	https://doi.org/10.1039/a701185g
State	Published - 1997

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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title = "An unusual imine (N=C) alkylalumination reaction",

abstract = "Addition of 3 equiv. of AlMe3 to a heptadentate Schiff-base ligand made from salicylaldehyde and bis(2-aminoethyl)-ethylenediamine (H3L1) results in an unusual alkylalumination of one of the imine bonds; addition of 2 equiv. of B(OMe)3 or AlMe3 to one of these ligands leads to the formation of bimetallic derivatives containing four- and five-coordinate metals, respectively.",

author = "Pingrong Wei and David Atwood",

year = "1997",

doi = "10.1039/a701185g",

language = "English",

pages = "1427--1428",

number = "15",

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T1 - An unusual imine (N=C) alkylalumination reaction

AU - Wei, Pingrong

AU - Atwood, David

PY - 1997

Y1 - 1997

N2 - Addition of 3 equiv. of AlMe3 to a heptadentate Schiff-base ligand made from salicylaldehyde and bis(2-aminoethyl)-ethylenediamine (H3L1) results in an unusual alkylalumination of one of the imine bonds; addition of 2 equiv. of B(OMe)3 or AlMe3 to one of these ligands leads to the formation of bimetallic derivatives containing four- and five-coordinate metals, respectively.

AB - Addition of 3 equiv. of AlMe3 to a heptadentate Schiff-base ligand made from salicylaldehyde and bis(2-aminoethyl)-ethylenediamine (H3L1) results in an unusual alkylalumination of one of the imine bonds; addition of 2 equiv. of B(OMe)3 or AlMe3 to one of these ligands leads to the formation of bimetallic derivatives containing four- and five-coordinate metals, respectively.

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UR - http://www.scopus.com/inward/citedby.url?scp=0003011497&partnerID=8YFLogxK

U2 - 10.1039/a701185g

DO - 10.1039/a701185g

M3 - Article

AN - SCOPUS:0003011497

SN - 1359-7345

SP - 1427

EP - 1428

JO - Chemical Communications

JF - Chemical Communications

IS - 15

ER -

An unusual imine (N=C) alkylalumination reaction

Abstract

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