An unusual imine (N=C) alkylalumination reaction

Pingrong Wei, David Atwood

Research output: Contribution to journalArticlepeer-review

24 Scopus citations

Abstract

Addition of 3 equiv. of AlMe3 to a heptadentate Schiff-base ligand made from salicylaldehyde and bis(2-aminoethyl)-ethylenediamine (H3L1) results in an unusual alkylalumination of one of the imine bonds; addition of 2 equiv. of B(OMe)3 or AlMe3 to one of these ligands leads to the formation of bimetallic derivatives containing four- and five-coordinate metals, respectively.

Original languageEnglish
Pages (from-to)1427-1428
Number of pages2
JournalChemical Communications
Issue number15
DOIs
StatePublished - 1997

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry (all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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