Abstract
Fast atom bombardment mass spectrometry has been used to analyse the cation complexation behaviour of a systematically varied array of crown and lariat ethers having one or two sidearms. Sandwich complexation, apparent when the cation is somewhat larger than the crown cavity, is observed for several systems but the presence of donor-group-containing sidearms in lariat ethers suppresses this phenomenon. Calcium cation complexation proved to be especially interesting.
| Original language | English |
|---|---|
| Pages (from-to) | 177-182 |
| Number of pages | 6 |
| Journal | Supramolecular Chemistry |
| Volume | 2 |
| Issue number | 2-3 |
| DOIs | |
| State | Published - Jul 1 1993 |
Bibliographical note
Funding Information:We gratefully acknowledge partial support of this work by a grant (GM 36262) to G.W.G.f rom the NIH.
Funding
We gratefully acknowledge partial support of this work by a grant (GM 36262) to G.W.G.f rom the NIH.
| Funders |
|---|
| National Institutes of Health (NIH) |
ASJC Scopus subject areas
- General Chemistry
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