Au137(SR)56nanomolecules: Composition, optical spectroscopy, electrochemistry and electrocatalytic reduction of CO2

Vijay Reddy Jupally, Asantha C. Dharmaratne, David Crasto, Aron J. Huckaba, Chanaka Kumara, Praneeth Reddy Nimmala, Nuwan Kothalawala, Jared H. Delcamp, Amala Dass

Research output: Contribution to journalArticlepeer-review

49 Scopus citations

Abstract

Au137(SR)56, a nanomolecule with a precise number of metal atoms and ligands, was synthesized. The composition was confirmed by MALDI and ESI mass spectrometry using three unique ligands (–SCH2CH2Ph, –SC6H13, and –SC4H9) and nano-alloys with Ag and Pd. The electrocatalytic properties were tested for CO2reduction.

Original languageEnglish
Pages (from-to)9895-9898
Number of pages4
JournalChemical Communications
Volume50
Issue number69
DOIs
StatePublished - Jul 31 2014

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry (all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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