Autonomic restoration of electrical conductivity using polymer-stabilized carbon nanotube and graphene microcapsules

Susan A. Odom; Timothy P. Tyler; Mary M. Caruso; Joshua A. Ritchey; Matthew V. Schulmerich; Scott J. Robinson; Rohit Bhargava; Nancy R. Sottos; Scott R. White; Mark C. Hersam; Jeffrey S. Moore

doi:10.1063/1.4737935

Autonomic restoration of electrical conductivity using polymer-stabilized carbon nanotube and graphene microcapsules

Susan A. Odom, Timothy P. Tyler, Mary M. Caruso, Joshua A. Ritchey, Matthew V. Schulmerich, Scott J. Robinson, Rohit Bhargava, Nancy R. Sottos, Scott R. White, Mark C. Hersam, Jeffrey S. Moore

Chemistry

Research output: Contribution to journal › Article › peer-review

57 Scopus citations

Abstract

We report the use of microcapsules containing suspensions of polymer-stabilized carbon nanotubes and/or graphene flakes for the autonomic restoration of conductivity in fractured gold lines. Multilayered samples were prepared in which microcapsules were embedded in layers of epoxy above and below a glass slide patterned with gold lines. Upon sample fracture, conductivity was lost as a crack formed in the gold line. Simultaneous release of carbon nanotubes and/or graphene suspensions from capsule cores restored conductivity in minutes. We suggest a healing mechanism in which the released carbon nanomaterials bridge gaps in the gold lines.

Original language	English
Article number	043106
Journal	Applied Physics Letters
Volume	101
Issue number	4
DOIs	https://doi.org/10.1063/1.4737935
State	Published - Jul 23 2012

Bibliographical note

Funding Information:
This work was supported as part of the Center for Electrical Energy Storage - Tailored Interfaces, an Energy Frontier Research Center funded by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences under Award No. (919 DOE ANL 9F-31921 NS) and the National Science Foundation under award number CHE 0957849. S.A.O. thanks the National Science Foundation for an American Competitiveness in Chemistry Fellowship under Award No. 0936888, funded by the American Recovery and Reinvestment Act. We thank Bharat Sankaran for e-beam deposition, Jason Goldman for assistance with photolithography, and Preston May for TGA analysis. We thank Benjamin Blaiszik, Sharlotte Kramer, and Nicolaas Vermeulen for helpful discussions.

Funding

This work was supported as part of the Center for Electrical Energy Storage - Tailored Interfaces, an Energy Frontier Research Center funded by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences under Award No. (919 DOE ANL 9F-31921 NS) and the National Science Foundation under award number CHE 0957849. S.A.O. thanks the National Science Foundation for an American Competitiveness in Chemistry Fellowship under Award No. 0936888, funded by the American Recovery and Reinvestment Act. We thank Bharat Sankaran for e-beam deposition, Jason Goldman for assistance with photolithography, and Preston May for TGA analysis. We thank Benjamin Blaiszik, Sharlotte Kramer, and Nicolaas Vermeulen for helpful discussions.

Funders	Funder number
Office of Basic Energy Sciences	919 DOE ANL 9F-31921 NS
U.S. Department of Energy Chinese Academy of Sciences Guangzhou Municipal Science and Technology Project Oak Ridge National Laboratory Extreme Science and Engineering Discovery Environment National Science Foundation National Energy Research Scientific Computing Center National Natural Science Foundation of China	0936888, CHE 0957849
U.S. Department of Energy Chinese Academy of Sciences Guangzhou Municipal Science and Technology Project Oak Ridge National Laboratory Extreme Science and Engineering Discovery Environment National Science Foundation National Energy Research Scientific Computing Center National Natural Science Foundation of China
U.S. Department of Energy Oak Ridge National Laboratory U.S. Department of Energy National Science Foundation National Energy Research Scientific Computing Center
National Science Foundation Office of International Science and Engineering

ASJC Scopus subject areas

Physics and Astronomy (miscellaneous)

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10.1063/1.4737935

Cite this

Odom, S. A., Tyler, T. P., Caruso, M. M., Ritchey, J. A., Schulmerich, M. V., Robinson, S. J., Bhargava, R., Sottos, N. R., White, S. R., Hersam, M. C., & Moore, J. S. (2012). Autonomic restoration of electrical conductivity using polymer-stabilized carbon nanotube and graphene microcapsules. Applied Physics Letters, 101(4), Article 043106. https://doi.org/10.1063/1.4737935

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abstract = "We report the use of microcapsules containing suspensions of polymer-stabilized carbon nanotubes and/or graphene flakes for the autonomic restoration of conductivity in fractured gold lines. Multilayered samples were prepared in which microcapsules were embedded in layers of epoxy above and below a glass slide patterned with gold lines. Upon sample fracture, conductivity was lost as a crack formed in the gold line. Simultaneous release of carbon nanotubes and/or graphene suspensions from capsule cores restored conductivity in minutes. We suggest a healing mechanism in which the released carbon nanomaterials bridge gaps in the gold lines.",

author = "Odom, \{Susan A.\} and Tyler, \{Timothy P.\} and Caruso, \{Mary M.\} and Ritchey, \{Joshua A.\} and Schulmerich, \{Matthew V.\} and Robinson, \{Scott J.\} and Rohit Bhargava and Sottos, \{Nancy R.\} and White, \{Scott R.\} and Hersam, \{Mark C.\} and Moore, \{Jeffrey S.\}",

note = "Funding Information: This work was supported as part of the Center for Electrical Energy Storage - Tailored Interfaces, an Energy Frontier Research Center funded by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences under Award No. (919 DOE ANL 9F-31921 NS) and the National Science Foundation under award number CHE 0957849. S.A.O. thanks the National Science Foundation for an American Competitiveness in Chemistry Fellowship under Award No. 0936888, funded by the American Recovery and Reinvestment Act. We thank Bharat Sankaran for e-beam deposition, Jason Goldman for assistance with photolithography, and Preston May for TGA analysis. We thank Benjamin Blaiszik, Sharlotte Kramer, and Nicolaas Vermeulen for helpful discussions. ",

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AU - Bhargava, Rohit

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AU - White, Scott R.

AU - Hersam, Mark C.

AU - Moore, Jeffrey S.

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Autonomic restoration of electrical conductivity using polymer-stabilized carbon nanotube and graphene microcapsules

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