Benzodichalcogenophenes with Perfluoroarene Termini

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37 Scopus citations

Abstract

(Chemical Equation Presented) Benzodichalcogenophenes are functionalized at their termini via SNAr reactions of their bismetalates with perfluoroarenes. The identities of X, Y, and W are varied to study the effects on LUMO energy levels and crystallization motif. X-ray crystallography reveals that nearly all new derivatives crystallize with coplanar ring systems within slipped 1D or 20 π-stacks.

Original languageEnglish
Pages (from-to)4421-4424
Number of pages4
JournalOrganic Letters
Volume10
Issue number20
DOIs
StatePublished - 2008

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry

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