Benzodichalcogenophenes with Perfluoroarene Termini

Yongfeng Wang; Sean R. Parkin; Mark D. Watson

doi:10.1021/ol801569m

Benzodichalcogenophenes with Perfluoroarene Termini

Yongfeng Wang, Sean R. Parkin, Mark D. Watson

Chemistry

Research output: Contribution to journal › Article › peer-review

42 Scopus citations

Abstract

(Chemical Equation Presented) Benzodichalcogenophenes are functionalized at their termini via SN_Ar reactions of their bismetalates with perfluoroarenes. The identities of X, Y, and W are varied to study the effects on LUMO energy levels and crystallization motif. X-ray crystallography reveals that nearly all new derivatives crystallize with coplanar ring systems within slipped 1D or 20 π-stacks.

Original language	English
Pages (from-to)	4421-4424
Number of pages	4
Journal	Organic Letters
Volume	10
Issue number	20
DOIs	https://doi.org/10.1021/ol801569m
State	Published - 2008

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

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10.1021/ol801569m

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title = "Benzodichalcogenophenes with Perfluoroarene Termini",

abstract = "(Chemical Equation Presented) Benzodichalcogenophenes are functionalized at their termini via SNAr reactions of their bismetalates with perfluoroarenes. The identities of X, Y, and W are varied to study the effects on LUMO energy levels and crystallization motif. X-ray crystallography reveals that nearly all new derivatives crystallize with coplanar ring systems within slipped 1D or 20 π-stacks.",

author = "Yongfeng Wang and Parkin, {Sean R.} and Watson, {Mark D.}",

year = "2008",

doi = "10.1021/ol801569m",

language = "English",

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T1 - Benzodichalcogenophenes with Perfluoroarene Termini

AU - Wang, Yongfeng

AU - Parkin, Sean R.

AU - Watson, Mark D.

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N2 - (Chemical Equation Presented) Benzodichalcogenophenes are functionalized at their termini via SNAr reactions of their bismetalates with perfluoroarenes. The identities of X, Y, and W are varied to study the effects on LUMO energy levels and crystallization motif. X-ray crystallography reveals that nearly all new derivatives crystallize with coplanar ring systems within slipped 1D or 20 π-stacks.

AB - (Chemical Equation Presented) Benzodichalcogenophenes are functionalized at their termini via SNAr reactions of their bismetalates with perfluoroarenes. The identities of X, Y, and W are varied to study the effects on LUMO energy levels and crystallization motif. X-ray crystallography reveals that nearly all new derivatives crystallize with coplanar ring systems within slipped 1D or 20 π-stacks.

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U2 - 10.1021/ol801569m

DO - 10.1021/ol801569m

M3 - Article

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JO - Organic Letters

JF - Organic Letters

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ER -

Benzodichalcogenophenes with Perfluoroarene Termini

Abstract

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