TY - JOUR
T1 - Biomimetic Self-Assembly of CoII-Seamed Hexameric Metal-Organic Nanocapsules
AU - Hu, Xiangquan
AU - Chai, Jie
AU - Zhang, Chen
AU - Lang, Jinxin
AU - Kelley, Steven P.
AU - Feng, Sisi
AU - Liu, Bin
AU - Atwood, David A.
AU - Atwood, Jerry L.
N1 - Publisher Copyright:
© 2019 American Chemical Society.
PY - 2019/6/12
Y1 - 2019/6/12
N2 - A CoII18L6 hexameric metal-organic nanocapsule (MONC) has been prepared and characterized using biomimetic self-assembly as the synthetic methodology. Akin to the biological behavior of zinc-finger proteins' release, uptake, and electrophilic substitution of Zn2+ ions, the assembly of this novel MONC has been accomplished by employing three sequential processes: assembly of the framework, metal ion insertion, and metal exchange, resulting in the formation of the CoII18L6 hexameric MONC. In this work, inspired by the biological behavior of metalloproteins, rational control of multiple complex supramolecular self-assembly has been achieved.
AB - A CoII18L6 hexameric metal-organic nanocapsule (MONC) has been prepared and characterized using biomimetic self-assembly as the synthetic methodology. Akin to the biological behavior of zinc-finger proteins' release, uptake, and electrophilic substitution of Zn2+ ions, the assembly of this novel MONC has been accomplished by employing three sequential processes: assembly of the framework, metal ion insertion, and metal exchange, resulting in the formation of the CoII18L6 hexameric MONC. In this work, inspired by the biological behavior of metalloproteins, rational control of multiple complex supramolecular self-assembly has been achieved.
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U2 - 10.1021/jacs.9b02857
DO - 10.1021/jacs.9b02857
M3 - Article
C2 - 31083943
AN - SCOPUS:85067283514
SN - 0002-7863
VL - 141
SP - 9151
EP - 9154
JO - Journal of the American Chemical Society
JF - Journal of the American Chemical Society
IS - 23
ER -