Biosynthetic short activation of the 2,3,6-trideoxysugar L-rhodinose

Jürgen Rohr; Sven Eric Wohlert; Carsten Oelkers; Andreas Kirschning; Monika Ries

doi:10.1039/a702125i

Biosynthetic short activation of the 2,3,6-trideoxysugar L-rhodinose

Jürgen Rohr, Sven Eric Wohlert, Carsten Oelkers, Andreas Kirschning, Monika Ries

Pharmaceutical Sciences

Research output: Contribution to journal › Article › peer-review

36 Scopus citations

Abstract

The successful incorporation of non-activated [2,3-²H₂]-L-rhodinose 4b into landomycin A 7 proves the existence of a short activation pathway for L-rhodinose 4; this result provides evidence of a general saving pathway for deoxysugar building blocks and their biosynthetic intermediates, respectively, which become accidentally deactivated during the biosynthetic deoxygenation cascades.

Original language	English
Pages (from-to)	973-974
Number of pages	2
Journal	Chemical Communications
Issue number	10
DOIs	https://doi.org/10.1039/a702125i
State	Published - May 21 1997

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
General Chemistry
Ceramics and Composites
Metals and Alloys
Materials Chemistry
Surfaces, Coatings and Films
Catalysis

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10.1039/a702125i

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abstract = "The successful incorporation of non-activated [2,3-2H2]-L-rhodinose 4b into landomycin A 7 proves the existence of a short activation pathway for L-rhodinose 4; this result provides evidence of a general saving pathway for deoxysugar building blocks and their biosynthetic intermediates, respectively, which become accidentally deactivated during the biosynthetic deoxygenation cascades.",

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AU - Rohr, Jürgen

AU - Wohlert, Sven Eric

AU - Oelkers, Carsten

AU - Kirschning, Andreas

AU - Ries, Monika

PY - 1997/5/21

Y1 - 1997/5/21

N2 - The successful incorporation of non-activated [2,3-2H2]-L-rhodinose 4b into landomycin A 7 proves the existence of a short activation pathway for L-rhodinose 4; this result provides evidence of a general saving pathway for deoxysugar building blocks and their biosynthetic intermediates, respectively, which become accidentally deactivated during the biosynthetic deoxygenation cascades.

AB - The successful incorporation of non-activated [2,3-2H2]-L-rhodinose 4b into landomycin A 7 proves the existence of a short activation pathway for L-rhodinose 4; this result provides evidence of a general saving pathway for deoxysugar building blocks and their biosynthetic intermediates, respectively, which become accidentally deactivated during the biosynthetic deoxygenation cascades.

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Biosynthetic short activation of the 2,3,6-trideoxysugar L-rhodinose

Abstract

ASJC Scopus subject areas

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