Biphenyl-4-yl 2,2,2-trichloroethyl sulfate

Xueshu Li; Sean Parkin; Michael W. Duffel; Larry W. Robertson; Hans Joachim Lehmler

doi:10.1107/S1600536810012845

Biphenyl-4-yl 2,2,2-trichloroethyl sulfate

Xueshu Li
, Sean Parkin
, Michael W. Duffel
, Larry W. Robertson
, Hans Joachim Lehmler

Chemistry

Research output: Contribution to journal › Article › peer-review

4 Scopus citations

Abstract

The molecular structure of the title compound, C₁₄H ₁₁C_l3O₄S, displays a biphenyl dihedral angle of 4.9 (2)° between the benzene rings, which is significantly smaller than the calculated dihedral angle of 41.2° of biphenyl derivatives without ortho substituents. The C_Ar - O bond length of 1.432 (4) Å is comparable with other sulfuric acid biphenyl-4-yl ester 2,2,2-trichloroether ester derivatives without electronegative substituents in the sulfated phenyl ring.

Original language	English
Pages (from-to)	o1073
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	66
Issue number	5
DOIs	https://doi.org/10.1107/S1600536810012845
State	Published - Apr 14 2010

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

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title = "Biphenyl-4-yl 2,2,2-trichloroethyl sulfate",

abstract = "The molecular structure of the title compound, C14H 11Cl3O4S, displays a biphenyl dihedral angle of 4.9 (2)° between the benzene rings, which is significantly smaller than the calculated dihedral angle of 41.2° of biphenyl derivatives without ortho substituents. The CAr - O bond length of 1.432 (4) {\AA} is comparable with other sulfuric acid biphenyl-4-yl ester 2,2,2-trichloroether ester derivatives without electronegative substituents in the sulfated phenyl ring.",

author = "Xueshu Li and Sean Parkin and Duffel, \{Michael W.\} and Robertson, \{Larry W.\} and Lehmler, \{Hans Joachim\}",

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doi = "10.1107/S1600536810012845",

language = "English",

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TY - JOUR

T1 - Biphenyl-4-yl 2,2,2-trichloroethyl sulfate

AU - Li, Xueshu

AU - Parkin, Sean

AU - Duffel, Michael W.

AU - Robertson, Larry W.

AU - Lehmler, Hans Joachim

PY - 2010/4/14

Y1 - 2010/4/14

N2 - The molecular structure of the title compound, C14H 11Cl3O4S, displays a biphenyl dihedral angle of 4.9 (2)° between the benzene rings, which is significantly smaller than the calculated dihedral angle of 41.2° of biphenyl derivatives without ortho substituents. The CAr - O bond length of 1.432 (4) Å is comparable with other sulfuric acid biphenyl-4-yl ester 2,2,2-trichloroether ester derivatives without electronegative substituents in the sulfated phenyl ring.

AB - The molecular structure of the title compound, C14H 11Cl3O4S, displays a biphenyl dihedral angle of 4.9 (2)° between the benzene rings, which is significantly smaller than the calculated dihedral angle of 41.2° of biphenyl derivatives without ortho substituents. The CAr - O bond length of 1.432 (4) Å is comparable with other sulfuric acid biphenyl-4-yl ester 2,2,2-trichloroether ester derivatives without electronegative substituents in the sulfated phenyl ring.

UR - https://www.scopus.com/pages/publications/77952085752

UR - https://www.scopus.com/pages/publications/77952085752#tab=citedBy

U2 - 10.1107/S1600536810012845

DO - 10.1107/S1600536810012845

M3 - Article

C2 - 21579128

AN - SCOPUS:77952085752

SN - 1600-5368

VL - 66

SP - o1073

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 5

ER -

Biphenyl-4-yl 2,2,2-trichloroethyl sulfate

Abstract

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