Biphenyldialkylsilyl chlorides: reagents for the formation of crystalline derivatives of small terminal alkynes

John Anthony; Francois Diederich

doi:10.1016/S0040-4039(00)79376-2

Biphenyldialkylsilyl chlorides: reagents for the formation of crystalline derivatives of small terminal alkynes

John Anthony, Francois Diederich

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Abstract

Biphenyldimethylsilyl chloride (BDMS-Cl) and biphenytdiisopropylsilyl chloride (BDIPS-Cl) are readily prepared reagents for the introduction of the BDMS and BDIPS protecting groups onto small terminal alkynes, leading to stable, solid, and easily recrystallizable derivatives of these thermally unstable molecules.

Original language	English
Pages (from-to)	3787-3790
Number of pages	4
Journal	Tetrahedron Letters
Volume	32
Issue number	31
DOIs	https://doi.org/10.1016/S0040-4039(00)79376-2
State	Published - Jul 29 1991

ASJC Scopus subject areas

Biochemistry
Drug Discovery
Organic Chemistry

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10.1016/S0040-4039(00)79376-2

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title = "Biphenyldialkylsilyl chlorides: reagents for the formation of crystalline derivatives of small terminal alkynes",

abstract = "Biphenyldimethylsilyl chloride (BDMS-Cl) and biphenytdiisopropylsilyl chloride (BDIPS-Cl) are readily prepared reagents for the introduction of the BDMS and BDIPS protecting groups onto small terminal alkynes, leading to stable, solid, and easily recrystallizable derivatives of these thermally unstable molecules.",

author = "John Anthony and Francois Diederich",

year = "1991",

month = jul,

day = "29",

doi = "10.1016/S0040-4039(00)79376-2",

language = "English",

volume = "32",

pages = "3787--3790",

number = "31",

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TY - JOUR

T1 - Biphenyldialkylsilyl chlorides

T2 - reagents for the formation of crystalline derivatives of small terminal alkynes

AU - Anthony, John

AU - Diederich, Francois

PY - 1991/7/29

Y1 - 1991/7/29

N2 - Biphenyldimethylsilyl chloride (BDMS-Cl) and biphenytdiisopropylsilyl chloride (BDIPS-Cl) are readily prepared reagents for the introduction of the BDMS and BDIPS protecting groups onto small terminal alkynes, leading to stable, solid, and easily recrystallizable derivatives of these thermally unstable molecules.

AB - Biphenyldimethylsilyl chloride (BDMS-Cl) and biphenytdiisopropylsilyl chloride (BDIPS-Cl) are readily prepared reagents for the introduction of the BDMS and BDIPS protecting groups onto small terminal alkynes, leading to stable, solid, and easily recrystallizable derivatives of these thermally unstable molecules.

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U2 - 10.1016/S0040-4039(00)79376-2

DO - 10.1016/S0040-4039(00)79376-2

M3 - Article

AN - SCOPUS:0025822939

SN - 0040-4039

VL - 32

SP - 3787

EP - 3790

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 31

ER -

Biphenyldialkylsilyl chlorides: reagents for the formation of crystalline derivatives of small terminal alkynes

Abstract

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