TY - JOUR
T1 - Bis[1-methoxy-2,2,2-tris(pyrazol-1-yl-κN 2)ethane] nickel(II) bis(trifluoromethanesulfonate) methanol disolvate
AU - Lyubartseva, Ganna
AU - Parkin, Sean
AU - Mallik, Uma Prasad
PY - 2013/10
Y1 - 2013/10
N2 - In the title salt, [Ni(C12H14N6O)2](CF3SO3)2·2CH3OH, the Ni II ion is coordinated by six N atoms from two tridentate 1-methoxy-2,2,2-tris(pyrazol-1-yl)ethane ligands in a distorted octahedral geometry. The NiII ion is situated on an inversion centre. The Ni - N distances range from 2.0589 (19) to 2.0757 (19) Å, intra-ligand N - Ni - N angles range from 84.50 (8) to 85.15 (8)°, and adjacent inter-ligand N - Ni - N angles range between 94.85 (8) and 95.50 (8)°. In the crystal, O - H⋯O hydrogen bonds between methanol solvent molecules and trifluoromethanesulfonate anions are observed.
AB - In the title salt, [Ni(C12H14N6O)2](CF3SO3)2·2CH3OH, the Ni II ion is coordinated by six N atoms from two tridentate 1-methoxy-2,2,2-tris(pyrazol-1-yl)ethane ligands in a distorted octahedral geometry. The NiII ion is situated on an inversion centre. The Ni - N distances range from 2.0589 (19) to 2.0757 (19) Å, intra-ligand N - Ni - N angles range from 84.50 (8) to 85.15 (8)°, and adjacent inter-ligand N - Ni - N angles range between 94.85 (8) and 95.50 (8)°. In the crystal, O - H⋯O hydrogen bonds between methanol solvent molecules and trifluoromethanesulfonate anions are observed.
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U2 - 10.1107/S1600536813024653
DO - 10.1107/S1600536813024653
M3 - Article
C2 - 24098170
AN - SCOPUS:84885107717
SN - 1600-5368
VL - 69
SP - m537
JO - Acta Crystallographica Section E: Structure Reports Online
JF - Acta Crystallographica Section E: Structure Reports Online
IS - 10
ER -