TY - JOUR
T1 - Bis(arylimidazole) Iridium Picolinate Emitters and Preferential Dipole Orientation in Films
AU - Huckaba, Aron J.
AU - Senes, Alessia
AU - Aghazada, Sadig
AU - Babaei, Azin
AU - Meskers, Stefan C.J.
AU - Zimmermann, Iwan
AU - Schouwink, Pascal
AU - Gasilova, Natalia
AU - Janssen, René A.J.
AU - Bolink, Henk J.
AU - Nazeeruddin, Mohammad Khaja
N1 - Publisher Copyright:
© 2018 American Chemical Society.
PY - 2018/3/31
Y1 - 2018/3/31
N2 - The straightforward synthesis and photophysical properties of a new series of heteroleptic iridium(III) bis(2-arylimidazole) picolinate complexes are reported. Each complex has been characterized by nuclear magnetic resonance, UV-vis, cyclic voltammetry, and photoluminescent angle dependency, and the emissive properties of each are described. The preferred orientation of transition dipoles in emitter/host thin films indicated more preferred orientation than homoleptic complex Ir(ppy)3.
AB - The straightforward synthesis and photophysical properties of a new series of heteroleptic iridium(III) bis(2-arylimidazole) picolinate complexes are reported. Each complex has been characterized by nuclear magnetic resonance, UV-vis, cyclic voltammetry, and photoluminescent angle dependency, and the emissive properties of each are described. The preferred orientation of transition dipoles in emitter/host thin films indicated more preferred orientation than homoleptic complex Ir(ppy)3.
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U2 - 10.1021/acsomega.8b00137
DO - 10.1021/acsomega.8b00137
M3 - Article
AN - SCOPUS:85043340806
VL - 3
SP - 2673
EP - 2682
JO - ACS Omega
JF - ACS Omega
IS - 3
ER -