TY - JOUR
T1 - Bis[tris(3,5-dimethyl-1H-pyrazol-1-yl-κN2)methyl]sodium trifluoromethanesulfonate
AU - Lyubartseva, Ganna
AU - Parkin, Sean
AU - Mallik, Uma Prasad
PY - 2012/7
Y1 - 2012/7
N2 - In the title salt, [Na(C16H22N6) 2]CF3SO3, the Na+ cation is coordinated by six N atoms from two tridentate tris(3,5-dimethylpyrazol-1-yl) methane ligands in a distorted octahedral geometry. The Na - N distances range from 2.427 (3) to 2.507 (3) Å, intra-ligand N - Na - N angles range from 74.71 (8) to 79.31 (9)°, and adjacent inter-ligand N - Na - N angles range between 100.42 (9) and 104.97 (9)°. The structure is twinned by inversion [occupancy factors = 0.50 (9)] and the trifluoromethanesulfonate anion is disordered, with two end-over-end orientations of unequal occupancy [0.781 (3) and 0.219 (3)].
AB - In the title salt, [Na(C16H22N6) 2]CF3SO3, the Na+ cation is coordinated by six N atoms from two tridentate tris(3,5-dimethylpyrazol-1-yl) methane ligands in a distorted octahedral geometry. The Na - N distances range from 2.427 (3) to 2.507 (3) Å, intra-ligand N - Na - N angles range from 74.71 (8) to 79.31 (9)°, and adjacent inter-ligand N - Na - N angles range between 100.42 (9) and 104.97 (9)°. The structure is twinned by inversion [occupancy factors = 0.50 (9)] and the trifluoromethanesulfonate anion is disordered, with two end-over-end orientations of unequal occupancy [0.781 (3) and 0.219 (3)].
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U2 - 10.1107/S1600536812028413
DO - 10.1107/S1600536812028413
M3 - Article
C2 - 22807792
AN - SCOPUS:84863580189
SN - 1600-5368
VL - 68
SP - m973
JO - Acta Crystallographica Section E: Structure Reports Online
JF - Acta Crystallographica Section E: Structure Reports Online
IS - 7
ER -