Bromination of the benzothioxanthene Bloc: Toward new π-conjugated systems for organic electronic applications

Pierre Josse, Shi Li, Sergey Dayneko, Damien Joly, Antoine Labrunie, Sylvie Dabos-Seignon, Magali Allain, Benjamin Siegler, Renaud Demadrille, Gregory C. Welch, Chad Risko, Philippe Blanchard, Clément Cabanetos

Research output: Contribution to journalArticlepeer-review

13 Scopus citations

Abstract

A selective and efficient method to afford a monobrominated benzothioxanthene (Br-BTXI) derivative is reported. Br-BTXI was extensively employed in common palladium catalyzed coupling reactions. Finally, as a proof of concept, a BTXI based molecular donor was synthesized and evaluated in bulk heterojunction solar cells.

Original languageEnglish
Pages (from-to)761-766
Number of pages6
JournalJournal of Materials Chemistry C
Volume6
Issue number4
DOIs
StatePublished - 2018

Bibliographical note

Funding Information:
The Ministère de la Recherche and the RFI LUMOMAT from the Région Pays de la Loire are acknowledged for the PhD grants of P. Josse and A. Labrunie respectively. Authors thank the PIAM (Plateforme d’Ingénierie et Analyses Moléculaires) of the University of Angers for the characterization of organic compounds. GCW acknowledges NSERC DG (435715-2013), CFI JELF (34102) and the Canadian Research Chairs Program. CR acknowledges the Department of the Navy, ONR (award no. N00014-16-1-2985) and the UK Vice President for start-up research funds. Supercomputing resources on the Lipscomb High Performance Computing Cluster were provided by the UK Information Technology Department and Center for Computational Sciences (CCS).

Publisher Copyright:
© 2018 The Royal Society of Chemistry.

ASJC Scopus subject areas

  • Chemistry (all)
  • Materials Chemistry

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