Catalytic dealkylation of phosphates with binuclear boron compounds

Timothy S. Keizer; Lauren J. De Pue; Sean Parkin; David A. Atwood

doi:10.1021/ja017360m

Catalytic dealkylation of phosphates with binuclear boron compounds

Timothy S. Keizer, Lauren J. De Pue, Sean Parkin, David A. Atwood

Chemistry

Research output: Contribution to journal › Article › peer-review

37 Scopus citations

Abstract

The Salen(^tBu) ligand and its derivatives were used to prepare binuclear boron complexes. These compounds have the formula, L(BBr₂)₂ (L = Salpen(^tBu) and Salben(^tBu)). These are formed from the reaction of the corresponding L[B(OMe)₂]₂ with BBr₃. They represent a new type of binuclear boron compound. These compounds are active towards the dealkylation of many phosphates. They are also catalytically active with a stoichiometric amount of BBr₃ to trimethylphosphate.

Original language	English
Pages (from-to)	1864-1865
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	124
Issue number	9
DOIs	https://doi.org/10.1021/ja017360m
State	Published - Mar 6 2002

ASJC Scopus subject areas

Catalysis
General Chemistry
Biochemistry
Colloid and Surface Chemistry

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title = "Catalytic dealkylation of phosphates with binuclear boron compounds",

abstract = "The Salen(tBu) ligand and its derivatives were used to prepare binuclear boron complexes. These compounds have the formula, L(BBr2)2 (L = Salpen(tBu) and Salben(tBu)). These are formed from the reaction of the corresponding L[B(OMe)2]2 with BBr3. They represent a new type of binuclear boron compound. These compounds are active towards the dealkylation of many phosphates. They are also catalytically active with a stoichiometric amount of BBr3 to trimethylphosphate.",

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T1 - Catalytic dealkylation of phosphates with binuclear boron compounds

AU - Keizer, Timothy S.

AU - De Pue, Lauren J.

AU - Parkin, Sean

AU - Atwood, David A.

PY - 2002/3/6

Y1 - 2002/3/6

N2 - The Salen(tBu) ligand and its derivatives were used to prepare binuclear boron complexes. These compounds have the formula, L(BBr2)2 (L = Salpen(tBu) and Salben(tBu)). These are formed from the reaction of the corresponding L[B(OMe)2]2 with BBr3. They represent a new type of binuclear boron compound. These compounds are active towards the dealkylation of many phosphates. They are also catalytically active with a stoichiometric amount of BBr3 to trimethylphosphate.

AB - The Salen(tBu) ligand and its derivatives were used to prepare binuclear boron complexes. These compounds have the formula, L(BBr2)2 (L = Salpen(tBu) and Salben(tBu)). These are formed from the reaction of the corresponding L[B(OMe)2]2 with BBr3. They represent a new type of binuclear boron compound. These compounds are active towards the dealkylation of many phosphates. They are also catalytically active with a stoichiometric amount of BBr3 to trimethylphosphate.

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EP - 1865

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 9

ER -

Catalytic dealkylation of phosphates with binuclear boron compounds

Abstract

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