Catalytic pyrolysis of spent coffee waste for upgrading sustainable bio-oil in a bubbling fluidized-bed reactor: Experimental and techno-economic analysis

Hoang Vu Ly, Boreum Lee, Jae Wook Sim, Quoc Khanh Tran, Seung Soo Kim, Jinsoo Kim, Boris Brigljević, Hyun Tae Hwang, Hankwon Lim

Research output: Contribution to journalArticlepeer-review

15 Scopus citations

Abstract

Spent coffee waste (SCW) is extremely attractive to be exploited and utilized as a material source for energy generation and chemical production. This study concerned bio-oil production via non-catalytic and catalytic fast pyrolysis using SCW in a bubbling fluidized-bed reactor (BFR). In particular, a comparative analysis of the quality of the bio-oil produced was conducted for non-catalytic (using silica sand as the bed material) and catalytic (using dolomite, HZSM-5, hematite, and magnetite as the catalyst) fast pyrolysis. Scale-up modeling confirmed using the experimental data was performed at a feed rate of 100 kg h−1 (1,000-fold capacity), which showed different orders in the quality of energy (hematite > magnetite > dolomite > HZSM-5 > silica, in order of energy from highest to lowest) owing to the realistic integration of the BFR with other components in plants, such as the combustor, compressor, and separator. Further, techno-economic analysis of scale-up system revealed that the unit production costs of bio-oil were 0.0151, 0.0034, 0.0143, 0.0095, and 0.0102 $ MJ−1 for silica, dolomite, HZSM-5, hematite, and magnetite, respectively (dolomite > hematite > magnetite > HZSM-5 > silica, in order of unit cost from lowest to highest). Among them, dolomite and hematite showed competitive unit production costs compared to the price of conventional crude oil (0.0098 $ MJ−1). The importance of coupling laboratory-scale experimental results with scale-up modeling and economic analysis has thus been demonstrated for practical feasibility studies of the SCW pyrolysis for bio-oil production.

Original languageEnglish
Article number130956
JournalChemical Engineering Journal
Volume427
DOIs
StatePublished - Jan 1 2022

Bibliographical note

Funding Information:
This work was supported by the National Research Foundation of Korea (NRF) grant funded by the Korea government( MSIT ) (No. 2020R1A2B5B01097547 ), Technology Development Program to Solve Climate Changes through the National Research Foundation of Korea (NRF) funded by the Ministry of Science, ICT ( NRF-2018M1A2A2026257 ), and the the Engineering Research Center of Excellence Program through the National Research Foundation (NRF), Ministry of Science and ICT, Republic of Korea ( NRF-2021R1A5A6002853 ).

Publisher Copyright:
© 2021 Elsevier B.V.

Keywords

  • Bio-oil production
  • Catalytic pyrolysis
  • Economic analysis
  • Process simulation
  • Scale up
  • Spent coffee waste

ASJC Scopus subject areas

  • Chemistry (all)
  • Environmental Chemistry
  • Chemical Engineering (all)
  • Industrial and Manufacturing Engineering

Fingerprint

Dive into the research topics of 'Catalytic pyrolysis of spent coffee waste for upgrading sustainable bio-oil in a bubbling fluidized-bed reactor: Experimental and techno-economic analysis'. Together they form a unique fingerprint.

Cite this