Chemical environment and Ce valence: Global trends in transition-metal compounds

R. A. Neifeld; M. Croft; T. Mihalisin; C. U. Segre; M. Madigan; M. S. Torikachvili; M. B. Maple; L. E. Delong

doi:10.1103/PhysRevB.32.6928

Chemical environment and Ce valence: Global trends in transition-metal compounds

R. A. Neifeld, M. Croft, T. Mihalisin, C. U. Segre, M. Madigan, M. S. Torikachvili, M. B. Maple, L. E. Delong

Physics And Astronomy

Research output: Contribution to journal › Article › peer-review

66 Scopus citations

Abstract

Results of LIII absorption spectroscopy measurements on a wide range of Cetransition-metal (T) compounds are presented and Ce valence-state estimates are made. We are able to identify extremely regular trends in the response of the Ce valence and Ce-T hybridization strength to systematic variations in the solid-state chemical environment. Our work facilitates identification of the specific elements in the T-metal electronic structure which drive the Ce valence-state change.

Original language	English
Pages (from-to)	6928-6931
Number of pages	4
Journal	Physical Review B
Volume	32
Issue number	10
DOIs	https://doi.org/10.1103/PhysRevB.32.6928
State	Published - 1985

ASJC Scopus subject areas

Condensed Matter Physics

Access to Document

10.1103/PhysRevB.32.6928

Cite this

@article{be7f8f95126d42a3b3e19076f2806710,

title = "Chemical environment and Ce valence: Global trends in transition-metal compounds",

abstract = "Results of LIII absorption spectroscopy measurements on a wide range of Cetransition-metal (T) compounds are presented and Ce valence-state estimates are made. We are able to identify extremely regular trends in the response of the Ce valence and Ce-T hybridization strength to systematic variations in the solid-state chemical environment. Our work facilitates identification of the specific elements in the T-metal electronic structure which drive the Ce valence-state change.",

author = "Neifeld, {R. A.} and M. Croft and T. Mihalisin and Segre, {C. U.} and M. Madigan and Torikachvili, {M. S.} and Maple, {M. B.} and Delong, {L. E.}",

year = "1985",

doi = "10.1103/PhysRevB.32.6928",

language = "English",

volume = "32",

pages = "6928--6931",

number = "10",

}

TY - JOUR

T1 - Chemical environment and Ce valence

T2 - Global trends in transition-metal compounds

AU - Neifeld, R. A.

AU - Croft, M.

AU - Mihalisin, T.

AU - Segre, C. U.

AU - Madigan, M.

AU - Torikachvili, M. S.

AU - Maple, M. B.

AU - Delong, L. E.

PY - 1985

Y1 - 1985

N2 - Results of LIII absorption spectroscopy measurements on a wide range of Cetransition-metal (T) compounds are presented and Ce valence-state estimates are made. We are able to identify extremely regular trends in the response of the Ce valence and Ce-T hybridization strength to systematic variations in the solid-state chemical environment. Our work facilitates identification of the specific elements in the T-metal electronic structure which drive the Ce valence-state change.

AB - Results of LIII absorption spectroscopy measurements on a wide range of Cetransition-metal (T) compounds are presented and Ce valence-state estimates are made. We are able to identify extremely regular trends in the response of the Ce valence and Ce-T hybridization strength to systematic variations in the solid-state chemical environment. Our work facilitates identification of the specific elements in the T-metal electronic structure which drive the Ce valence-state change.

UR - http://www.scopus.com/inward/record.url?scp=0001031212&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0001031212&partnerID=8YFLogxK

U2 - 10.1103/PhysRevB.32.6928

DO - 10.1103/PhysRevB.32.6928

M3 - Article

AN - SCOPUS:0001031212

SN - 0163-1829

VL - 32

SP - 6928

EP - 6931

JO - Physical Review B

JF - Physical Review B

IS - 10

ER -

Chemical environment and Ce valence: Global trends in transition-metal compounds

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this