Chemical environment and Ce valence: Global trends in transition-metal compounds

R. A. Neifeld; M. Croft; T. Mihalisin; C. U. Segre; M. Madigan; M. S. Torikachvili; M. B. Maple; L. E. Delong

doi:10.1103/PhysRevB.32.6928

Chemical environment and Ce valence: Global trends in transition-metal compounds

R. A. Neifeld, M. Croft, T. Mihalisin, C. U. Segre, M. Madigan, M. S. Torikachvili, M. B. Maple, L. E. Delong

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Abstract

Results of LIII absorption spectroscopy measurements on a wide range of Cetransition-metal (T) compounds are presented and Ce valence-state estimates are made. We are able to identify extremely regular trends in the response of the Ce valence and Ce-T hybridization strength to systematic variations in the solid-state chemical environment. Our work facilitates identification of the specific elements in the T-metal electronic structure which drive the Ce valence-state change.

Original language	English
Pages (from-to)	6928-6931
Number of pages	4
Journal	Physical Review B
Volume	32
Issue number	10
DOIs	https://doi.org/10.1103/PhysRevB.32.6928
State	Published - 1985

ASJC Scopus subject areas

Condensed Matter Physics

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10.1103/PhysRevB.32.6928

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abstract = "Results of LIII absorption spectroscopy measurements on a wide range of Cetransition-metal (T) compounds are presented and Ce valence-state estimates are made. We are able to identify extremely regular trends in the response of the Ce valence and Ce-T hybridization strength to systematic variations in the solid-state chemical environment. Our work facilitates identification of the specific elements in the T-metal electronic structure which drive the Ce valence-state change.",

author = "Neifeld, \{R. A.\} and M. Croft and T. Mihalisin and Segre, \{C. U.\} and M. Madigan and Torikachvili, \{M. S.\} and Maple, \{M. B.\} and Delong, \{L. E.\}",

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language = "English",

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T2 - Global trends in transition-metal compounds

AU - Neifeld, R. A.

AU - Croft, M.

AU - Mihalisin, T.

AU - Segre, C. U.

AU - Madigan, M.

AU - Torikachvili, M. S.

AU - Maple, M. B.

AU - Delong, L. E.

PY - 1985

Y1 - 1985

N2 - Results of LIII absorption spectroscopy measurements on a wide range of Cetransition-metal (T) compounds are presented and Ce valence-state estimates are made. We are able to identify extremely regular trends in the response of the Ce valence and Ce-T hybridization strength to systematic variations in the solid-state chemical environment. Our work facilitates identification of the specific elements in the T-metal electronic structure which drive the Ce valence-state change.

AB - Results of LIII absorption spectroscopy measurements on a wide range of Cetransition-metal (T) compounds are presented and Ce valence-state estimates are made. We are able to identify extremely regular trends in the response of the Ce valence and Ce-T hybridization strength to systematic variations in the solid-state chemical environment. Our work facilitates identification of the specific elements in the T-metal electronic structure which drive the Ce valence-state change.

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DO - 10.1103/PhysRevB.32.6928

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JO - Physical Review B

JF - Physical Review B

IS - 10

ER -

Chemical environment and Ce valence: Global trends in transition-metal compounds

Abstract

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