Chiral metal-containing polymers

Edith C. Glazer, Yitzhak Tor

Research output: Contribution to journalConference articlepeer-review

9 Scopus citations

Abstract

A program aimed at the synthesis and characterization of conjugated multimetallic arrays and polymers containing d6 transition metal ions, in particular RuII and Os polypyridine complexes, have been initiated. The relative kinetic stability and well characterized photophysics and redox chemistry of these complexes make them attractive for the construction of advanced materials that are responsive to external stimuli. It is demonstrated that difunctionalized coordination RuII complexes can be used as enantiomerically pure building blocks and cross coupled to difunctionalized aromatic alkynes to give conjugated multimetallic arrays and polymers.

Original languageEnglish
Pages (from-to)513-514
Number of pages2
JournalAmerican Chemical Society, Polymer Preprints, Division of Polymer Chemistry
Volume40
Issue number1
StatePublished - Mar 1999
EventProceedings of the 1999 ACS Anaheim Meeting - Anaheim, CA, USA
Duration: Mar 21 1999Mar 25 1999

ASJC Scopus subject areas

  • Polymers and Plastics

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