TY - JOUR
T1 - Compatibility of proximal functionality with the manganese triacetate oxidation of hindered enones in podocarpane-like systems
AU - Gross, Raymond S.
AU - Kawada, Kenji
AU - Kim, Moonsun
AU - Watt, David S.
PY - 1989/4/1
Y1 - 1989/4/1
N2 - The scope of the manganese triacetate oxidation of enones to a’-acetoxyenones was examined using various 18,19-desmethylpodocarp-13-en-12-ones: the process will not accommodate hydroxyl or ketone functionality elsewhere in the substrate but will accomodate ester, ether, and acetal functionality provided that it does not sterically block the oxidation site.
AB - The scope of the manganese triacetate oxidation of enones to a’-acetoxyenones was examined using various 18,19-desmethylpodocarp-13-en-12-ones: the process will not accommodate hydroxyl or ketone functionality elsewhere in the substrate but will accomodate ester, ether, and acetal functionality provided that it does not sterically block the oxidation site.
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U2 - 10.1080/00397918908054515
DO - 10.1080/00397918908054515
M3 - Article
AN - SCOPUS:84972893088
SN - 0039-7911
VL - 19
SP - 1127
EP - 1135
JO - Synthetic Communications
JF - Synthetic Communications
IS - 7-8
ER -