Controlled synthesis, efficient purification, and electrochemical characterization of arc-discharge carbon nano-onions

Rituraj Borgohain, Juchan Yang, John P. Selegue, Doo Young Kim

Research output: Contribution to journalArticlepeer-review

93 Scopus citations

Abstract

Arc-produced carbon nano-onions (A-CNOs), with a hollow core surrounded by multilayered sp2 carbon shells, possess unique structural and electronic properties. While nanodiamond derived CNOs (5-7 nm) are attracting significant attentions, for A-CNOs (20-50 nm) controlling the growth and separating them from carbon impurities are the major challenges that impede further study and application of these materials. We have addressed these issues; first by designing an in-house automated underwater arc discharge apparatus to control the arc plasma that produces homogeneous A-CNOs (diameter 25-35 nm) with minimal carbon impurities. Secondly, for further purification we have developed a very efficient method by utilizing the strong preferential adsorption of polyoxometalates. A-CNO growth and purification were investigated using thermogravimetric analysis (TGA), high-resolution transmission electron microscopy (HRTEM), Raman spectroscopy and X-ray diffraction (XRD). Furthermore, the electrochemical properties and electrocatalytic activities of purified A-CNOs were investigated with various redox species including neurotransmitter molecules. Compared to glassy carbon (GC) electrode, A-CNO showed excellent electrochemical performances including larger faradaic currents and facilitated electron-transfer kinetics. Controlled synthesis, efficient purification and the excellent electrocatalytic activities of A-CNOs reported herein will enable the utilization of these materials for various applications including biosensing, fuel-cell catalysts and energy-storage devices.

Original languageEnglish
Pages (from-to)272-284
Number of pages13
JournalCarbon
Volume66
DOIs
StatePublished - Jan 2014

Bibliographical note

Funding Information:
We thank the National Science Foundation (Center for Advanced Materials, Grant EPS-0814194 , JPS) and the University of Kentucky (faculty start-up grant, DYK) for support of this research. We thank Mahendra Sreeramoju for the powder conductivity measurement of A-CNOs.

ASJC Scopus subject areas

  • General Chemistry
  • General Materials Science

Fingerprint

Dive into the research topics of 'Controlled synthesis, efficient purification, and electrochemical characterization of arc-discharge carbon nano-onions'. Together they form a unique fingerprint.

Cite this