TY - JOUR
T1 - Crystal structure of 4,5-bis(3,4,5-trimethoxyphenyl)-2H-1,2,3-triazole methanol monosolvate
AU - Madadi, Nikhil Reddy
AU - Penthala, Narsimha Reddy
AU - Bommagani, Shobanbabu
AU - Parkin, Sean
AU - Crooks, Peter A.
PY - 2014/10/1
Y1 - 2014/10/1
N2 - The title compound, C20H23N3O6 CH3OH, was synthesized by [3 + 2] cycloaddition of (Z)-2,3-bis(3,4,5-trimethoxyphenyl)acrylonitrile with sodium azide and ammonium chloride in DMF/water. The central nitrogen of the triazole ring is protonated. The dihedral angles between the triazole ring and the 3,4,5-trimethoxyphenyl ring planes are 34.31(4) and 45.03(5)°, while that between the 3,4,5-trimethoxyphenyl rings is 51.87(5)°. In the crystal, the molecules, along with two methanol solvent molecules are linked into an R4 4(10) centrosymmetric dimer by N-H⋯O and O-H⋯N hydrogen bonds.
AB - The title compound, C20H23N3O6 CH3OH, was synthesized by [3 + 2] cycloaddition of (Z)-2,3-bis(3,4,5-trimethoxyphenyl)acrylonitrile with sodium azide and ammonium chloride in DMF/water. The central nitrogen of the triazole ring is protonated. The dihedral angles between the triazole ring and the 3,4,5-trimethoxyphenyl ring planes are 34.31(4) and 45.03(5)°, while that between the 3,4,5-trimethoxyphenyl rings is 51.87(5)°. In the crystal, the molecules, along with two methanol solvent molecules are linked into an R4 4(10) centrosymmetric dimer by N-H⋯O and O-H⋯N hydrogen bonds.
KW - 1,2,3-triazole
KW - crystal structure
KW - hydrogen bonds
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U2 - 10.1107/S1600536814020911
DO - 10.1107/S1600536814020911
M3 - Article
AN - SCOPUS:84907902881
SN - 1600-5368
VL - 70
SP - o1128-o1129
JO - Acta Crystallographica Section E: Structure Reports Online
JF - Acta Crystallographica Section E: Structure Reports Online
IS - 10
ER -