Crystal structure of {(but-3-en-1-yl) bis[(pyridin-2-yl) methyl]amine-κ3N,N′,N″}dichlorido-copper(II) diethyl ether hemisolvate

Katherine A. Bussey; Jennifer R. Connell; Annie R. McGlone; Margaret E. Mraz; Kayode D. Oshin; Tomislav Pintauer; Allen G. Oliver; S. Parkin

doi:10.1107/S2056989015003448

Crystal structure of {(but-3-en-1-yl) bis[(pyridin-2-yl) methyl]amine-κ³N,N′,N″}dichlorido-copper(II) diethyl ether hemisolvate

Katherine A. Bussey, Jennifer R. Connell, Annie R. McGlone, Margaret E. Mraz, Kayode D. Oshin, Tomislav Pintauer, Allen G. Oliver, S. Parkin

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

The five-coordinate Cu^II atom in the title complex [CuCl₂(C₁₆H₁₉N₃)]·-0.5C₄H₁₀O, adopts a near-ideal square-pyramidal geometry (τ-5 = 0.01). The apical Cu - Cl distance is 0.2626 (6) Å longer than the basal Cu - Cl distance. Weak C - H⋯Cl interactions between pyridine rings and the Cl atoms of adjacent complex molecules are present. The solvent molecule, located on a twofold rotation axis, is situated in the voids of this arrangement. Copper atoms coordinated by tridentate nitrogen-containing ligands have been found to be excellent promoters of Atom Transfer Radical Addition (ATRA) reactions.

Original language	English
Pages (from-to)	309-311
Number of pages	3
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	71
Issue number	3
DOIs	https://doi.org/10.1107/S2056989015003448
State	Published - Mar 1 2015

Keywords

Atom Transfer Radical Addition (ATRA) reactions
Crystal structure
Five-coordinate copper(II) complex

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

Access to Document

10.1107/S2056989015003448

Cite this

Bussey, K. A., Connell, J. R., McGlone, A. R., Mraz, M. E., Oshin, K. D., Pintauer, T., Oliver, A. G., & Parkin, S. (2015). Crystal structure of {(but-3-en-1-yl) bis[(pyridin-2-yl) methyl]amine-κ³N,N′,N″}dichlorido-copper(II) diethyl ether hemisolvate. Acta Crystallographica Section E: Structure Reports Online, 71(3), 309-311. https://doi.org/10.1107/S2056989015003448

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title = "Crystal structure of {(but-3-en-1-yl) bis[(pyridin-2-yl) methyl]amine-κ3N,N′,N″}dichlorido-copper(II) diethyl ether hemisolvate",

abstract = "The five-coordinate CuII atom in the title complex [CuCl2(C16H19N3)]·-0.5C4H10O, adopts a near-ideal square-pyramidal geometry (τ-5 = 0.01). The apical Cu - Cl distance is 0.2626 (6) {\AA} longer than the basal Cu - Cl distance. Weak C - H⋯Cl interactions between pyridine rings and the Cl atoms of adjacent complex molecules are present. The solvent molecule, located on a twofold rotation axis, is situated in the voids of this arrangement. Copper atoms coordinated by tridentate nitrogen-containing ligands have been found to be excellent promoters of Atom Transfer Radical Addition (ATRA) reactions.",

keywords = "Atom Transfer Radical Addition (ATRA) reactions, Crystal structure, Five-coordinate copper(II) complex",

author = "Bussey, {Katherine A.} and Connell, {Jennifer R.} and McGlone, {Annie R.} and Mraz, {Margaret E.} and Oshin, {Kayode D.} and Tomislav Pintauer and Oliver, {Allen G.} and S. Parkin",

year = "2015",

month = mar,

day = "1",

doi = "10.1107/S2056989015003448",

language = "English",

volume = "71",

pages = "309--311",

number = "3",

}

Crystal structure of {(but-3-en-1-yl) bis[(pyridin-2-yl) methyl]amine-κ³N,N′,N″}dichlorido-copper(II) diethyl ether hemisolvate. / Bussey, Katherine A.; Connell, Jennifer R.; McGlone, Annie R. et al.
In: Acta Crystallographica Section E: Structure Reports Online, Vol. 71, No. 3, 01.03.2015, p. 309-311.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Crystal structure of {(but-3-en-1-yl) bis[(pyridin-2-yl) methyl]amine-κ3N,N′,N″}dichlorido-copper(II) diethyl ether hemisolvate

AU - Bussey, Katherine A.

AU - Connell, Jennifer R.

AU - McGlone, Annie R.

AU - Mraz, Margaret E.

AU - Oshin, Kayode D.

AU - Pintauer, Tomislav

AU - Oliver, Allen G.

AU - Parkin, S.

PY - 2015/3/1

Y1 - 2015/3/1

N2 - The five-coordinate CuII atom in the title complex [CuCl2(C16H19N3)]·-0.5C4H10O, adopts a near-ideal square-pyramidal geometry (τ-5 = 0.01). The apical Cu - Cl distance is 0.2626 (6) Å longer than the basal Cu - Cl distance. Weak C - H⋯Cl interactions between pyridine rings and the Cl atoms of adjacent complex molecules are present. The solvent molecule, located on a twofold rotation axis, is situated in the voids of this arrangement. Copper atoms coordinated by tridentate nitrogen-containing ligands have been found to be excellent promoters of Atom Transfer Radical Addition (ATRA) reactions.

AB - The five-coordinate CuII atom in the title complex [CuCl2(C16H19N3)]·-0.5C4H10O, adopts a near-ideal square-pyramidal geometry (τ-5 = 0.01). The apical Cu - Cl distance is 0.2626 (6) Å longer than the basal Cu - Cl distance. Weak C - H⋯Cl interactions between pyridine rings and the Cl atoms of adjacent complex molecules are present. The solvent molecule, located on a twofold rotation axis, is situated in the voids of this arrangement. Copper atoms coordinated by tridentate nitrogen-containing ligands have been found to be excellent promoters of Atom Transfer Radical Addition (ATRA) reactions.

KW - Atom Transfer Radical Addition (ATRA) reactions

KW - Crystal structure

KW - Five-coordinate copper(II) complex

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