Crystal structure of trans-dihydrido-bis[tris(dimethylamino) phosphane-κP]-platinum(II)

Emma L. Downs; Lev N. Zakharov; David R. Tyler; S. Parkin

doi:10.1107/S2056989015004351

Crystal structure of trans-dihydrido-bis[tris(dimethylamino) phosphane-κP]-platinum(II)

Emma L. Downs, Lev N. Zakharov, David R. Tyler, S. Parkin

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

The molecule of the title compound, [PtH₂(C₆H₁₈N₃P)₂], has a centrosymmetric square-planar structure in which the Pt^II atom is bonded to two H and two P atoms in a mutually trans configuration. The P_t^II atom sits on an inversion center and thus the asymmetric unit contains only half the molecule. The Pt - P and Pt - H distances are 2.2574 (10) and 1.49 (7) Å, respectively.

Original language	English
Pages (from-to)	m83-m84
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	71
Issue number	4
DOIs	https://doi.org/10.1107/S2056989015004351
State	Published - Apr 1 2015

Keywords

Crystal structure
Ligand-assisted hydration
Nitrile hydration
Platinum(II) complex
Tris(dimethylamino) phosphane

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

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10.1107/S2056989015004351

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title = "Crystal structure of trans-dihydrido-bis[tris(dimethylamino) phosphane-κP]-platinum(II)",

abstract = "The molecule of the title compound, [PtH2(C6H18N3P)2], has a centrosymmetric square-planar structure in which the PtII atom is bonded to two H and two P atoms in a mutually trans configuration. The PtII atom sits on an inversion center and thus the asymmetric unit contains only half the molecule. The Pt - P and Pt - H distances are 2.2574 (10) and 1.49 (7) {\AA}, respectively.",

keywords = "Crystal structure, Ligand-assisted hydration, Nitrile hydration, Platinum(II) complex, Tris(dimethylamino) phosphane",

author = "Downs, {Emma L.} and Zakharov, {Lev N.} and Tyler, {David R.} and S. Parkin",

year = "2015",

month = apr,

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doi = "10.1107/S2056989015004351",

language = "English",

volume = "71",

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TY - JOUR

T1 - Crystal structure of trans-dihydrido-bis[tris(dimethylamino) phosphane-κP]-platinum(II)

AU - Downs, Emma L.

AU - Zakharov, Lev N.

AU - Tyler, David R.

AU - Parkin, S.

PY - 2015/4/1

Y1 - 2015/4/1

N2 - The molecule of the title compound, [PtH2(C6H18N3P)2], has a centrosymmetric square-planar structure in which the PtII atom is bonded to two H and two P atoms in a mutually trans configuration. The PtII atom sits on an inversion center and thus the asymmetric unit contains only half the molecule. The Pt - P and Pt - H distances are 2.2574 (10) and 1.49 (7) Å, respectively.

AB - The molecule of the title compound, [PtH2(C6H18N3P)2], has a centrosymmetric square-planar structure in which the PtII atom is bonded to two H and two P atoms in a mutually trans configuration. The PtII atom sits on an inversion center and thus the asymmetric unit contains only half the molecule. The Pt - P and Pt - H distances are 2.2574 (10) and 1.49 (7) Å, respectively.

KW - Crystal structure

KW - Ligand-assisted hydration

KW - Nitrile hydration

KW - Platinum(II) complex

KW - Tris(dimethylamino) phosphane

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U2 - 10.1107/S2056989015004351

DO - 10.1107/S2056989015004351

M3 - Article

AN - SCOPUS:84928138782

SN - 1600-5368

VL - 71

SP - m83-m84

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 4

ER -

Crystal structure of trans-dihydrido-bis[tris(dimethylamino) phosphane-κP]-platinum(II)

Abstract

Keywords

ASJC Scopus subject areas

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