Crystal structures of fac-trichloridotris(trimethyl-phosphane-κP)rhodium(III) monohydrate and fac-trichloridotris(trimethylphosphane-κP)rhodium(III) methanol hemisolvate: Rhodium structures that are isotypic with their iridium analogs

Joseph S. Merola; Marion A. Franks; S. Parkin

doi:10.1107/S2056989015001516

Crystal structures of fac-trichloridotris(trimethyl-phosphane-κP)rhodium(III) monohydrate and fac-trichloridotris(trimethylphosphane-κP)rhodium(III) methanol hemisolvate: Rhodium structures that are isotypic with their iridium analogs

Joseph S. Merola
, Marion A. Franks
, S. Parkin

Chemistry

Research output: Contribution to journal › Article › peer-review

4 Scopus citations

Abstract

The crystal structures of two solvates offac-trichloridotris(trimethylphosphane-κP)rhodium(III) are reported, i.e. one with water in the crystal lattice, fac-[RhCl₃(Me₃P)₃]·H₂O, and one with methanol in the crystal lattice, fac-[RhCl₃(Me₃P)₃]·0.5CH₃OH. These rhodium compounds exhibit distorted octahedral coordination spheres at the metal and are isotypic with the analogous iridium compounds previously reported by us [Merola et al. (2013). Polyhedron, 54, 67-73]. Comparison is made between the rhodium and iridium compounds, highlighting their isostructural relationships.

Original language	English
Pages (from-to)	226-230
Number of pages	5
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	71
Issue number	2
DOIs	https://doi.org/10.1107/S2056989015001516
State	Published - Feb 1 2015

Funding

Funders	Funder number
National Science Foundation (NSF)	CHE-902244

Keywords

Crystal structure
Iridium
Isotypism
Phosphane ligands
Rhodium

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

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Merola, J. S., Franks, M. A., & Parkin, S. (2015). Crystal structures of fac-trichloridotris(trimethyl-phosphane-κP)rhodium(III) monohydrate and fac-trichloridotris(trimethylphosphane-κP)rhodium(III) methanol hemisolvate: Rhodium structures that are isotypic with their iridium analogs. Acta Crystallographica Section E: Structure Reports Online, 71(2), 226-230. https://doi.org/10.1107/S2056989015001516

Merola, Joseph S. ; Franks, Marion A. ; Parkin, S. / Crystal structures of fac-trichloridotris(trimethyl-phosphane-κP)rhodium(III) monohydrate and fac-trichloridotris(trimethylphosphane-κP)rhodium(III) methanol hemisolvate : Rhodium structures that are isotypic with their iridium analogs. In: Acta Crystallographica Section E: Structure Reports Online. 2015 ; Vol. 71, No. 2. pp. 226-230.

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title = "Crystal structures of fac-trichloridotris(trimethyl-phosphane-κP)rhodium(III) monohydrate and fac-trichloridotris(trimethylphosphane-κP)rhodium(III) methanol hemisolvate: Rhodium structures that are isotypic with their iridium analogs",

abstract = "The crystal structures of two solvates offac-trichloridotris(trimethylphosphane-κP)rhodium(III) are reported, i.e. one with water in the crystal lattice, fac-[RhCl3(Me3P)3]·H2O, and one with methanol in the crystal lattice, fac-[RhCl3(Me3P)3]·0.5CH3OH. These rhodium compounds exhibit distorted octahedral coordination spheres at the metal and are isotypic with the analogous iridium compounds previously reported by us [Merola et al. (2013). Polyhedron, 54, 67-73]. Comparison is made between the rhodium and iridium compounds, highlighting their isostructural relationships.",

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Merola, JS, Franks, MA & Parkin, S 2015, 'Crystal structures of fac-trichloridotris(trimethyl-phosphane-κP)rhodium(III) monohydrate and fac-trichloridotris(trimethylphosphane-κP)rhodium(III) methanol hemisolvate: Rhodium structures that are isotypic with their iridium analogs', Acta Crystallographica Section E: Structure Reports Online, vol. 71, no. 2, pp. 226-230. https://doi.org/10.1107/S2056989015001516

Crystal structures of fac-trichloridotris(trimethyl-phosphane-κP)rhodium(III) monohydrate and fac-trichloridotris(trimethylphosphane-κP)rhodium(III) methanol hemisolvate: Rhodium structures that are isotypic with their iridium analogs. / Merola, Joseph S.; Franks, Marion A.; Parkin, S.
In: Acta Crystallographica Section E: Structure Reports Online, Vol. 71, No. 2, 01.02.2015, p. 226-230.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Crystal structures of fac-trichloridotris(trimethyl-phosphane-κP)rhodium(III) monohydrate and fac-trichloridotris(trimethylphosphane-κP)rhodium(III) methanol hemisolvate

T2 - Rhodium structures that are isotypic with their iridium analogs

AU - Merola, Joseph S.

AU - Franks, Marion A.

AU - Parkin, S.

PY - 2015/2/1

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N2 - The crystal structures of two solvates offac-trichloridotris(trimethylphosphane-κP)rhodium(III) are reported, i.e. one with water in the crystal lattice, fac-[RhCl3(Me3P)3]·H2O, and one with methanol in the crystal lattice, fac-[RhCl3(Me3P)3]·0.5CH3OH. These rhodium compounds exhibit distorted octahedral coordination spheres at the metal and are isotypic with the analogous iridium compounds previously reported by us [Merola et al. (2013). Polyhedron, 54, 67-73]. Comparison is made between the rhodium and iridium compounds, highlighting their isostructural relationships.

AB - The crystal structures of two solvates offac-trichloridotris(trimethylphosphane-κP)rhodium(III) are reported, i.e. one with water in the crystal lattice, fac-[RhCl3(Me3P)3]·H2O, and one with methanol in the crystal lattice, fac-[RhCl3(Me3P)3]·0.5CH3OH. These rhodium compounds exhibit distorted octahedral coordination spheres at the metal and are isotypic with the analogous iridium compounds previously reported by us [Merola et al. (2013). Polyhedron, 54, 67-73]. Comparison is made between the rhodium and iridium compounds, highlighting their isostructural relationships.

KW - Crystal structure

KW - Iridium

KW - Isotypism

KW - Phosphane ligands

KW - Rhodium

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Merola JS, Franks MA, Parkin S. Crystal structures of fac-trichloridotris(trimethyl-phosphane-κP)rhodium(III) monohydrate and fac-trichloridotris(trimethylphosphane-κP)rhodium(III) methanol hemisolvate: Rhodium structures that are isotypic with their iridium analogs. Acta Crystallographica Section E: Structure Reports Online. 2015 Feb 1;71(2):226-230. doi: 10.1107/S2056989015001516

Crystal structures of fac-trichloridotris(trimethyl-phosphane-κP)rhodium(III) monohydrate and fac-trichloridotris(trimethylphosphane-κP)rhodium(III) methanol hemisolvate: Rhodium structures that are isotypic with their iridium analogs

Abstract

Funding

Keywords

ASJC Scopus subject areas

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