Abstract
The hydrogen-deuterium exchange reaction was performed for hydrogenation of D 5-1-pentene (4,4,5,5,5) under realistic cobalt Fischer-Tropsch synthesis conditions. In the presence of CO, the added deutero-1-pentene did not show any significant H/D exchange but a step-wise H/D exchange occurs when CO was replaced with N 2. The inhibition effects of CO and other FT products on H/D exchange of D 5-1-pentene and a pressure dependency effect on H/D exchange are observed. Graphical Abstract: [Figure not available: see fulltext.]
Original language | English |
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Pages (from-to) | 190-194 |
Number of pages | 5 |
Journal | Catalysis Letters |
Volume | 142 |
Issue number | 2 |
DOIs | |
State | Published - Feb 2012 |
Bibliographical note
Funding Information:Acknowledgments The work was supported by funding from the Commonwealth of Kentucky.
Keywords
- Cobalt
- Deuterium exchange
- Deutero-1-pentene
- Fischer-Tropsch
- Hydrogenation
ASJC Scopus subject areas
- Catalysis
- General Chemistry