Deuterium exchange study for hydrogenation of D 5-1-pentene (4,4,5,5,5) over conventional cobalt Fischer-Tropsch catalyst

Muthu Kumaran Gnanamani, Wilson D. Shafer, Burtron H. Davis

Research output: Contribution to journalArticlepeer-review

1 Scopus citations

Abstract

The hydrogen-deuterium exchange reaction was performed for hydrogenation of D 5-1-pentene (4,4,5,5,5) under realistic cobalt Fischer-Tropsch synthesis conditions. In the presence of CO, the added deutero-1-pentene did not show any significant H/D exchange but a step-wise H/D exchange occurs when CO was replaced with N 2. The inhibition effects of CO and other FT products on H/D exchange of D 5-1-pentene and a pressure dependency effect on H/D exchange are observed. Graphical Abstract: [Figure not available: see fulltext.]

Original languageEnglish
Pages (from-to)190-194
Number of pages5
JournalCatalysis Letters
Volume142
Issue number2
DOIs
StatePublished - Feb 2012

Bibliographical note

Funding Information:
Acknowledgments The work was supported by funding from the Commonwealth of Kentucky.

Keywords

  • Cobalt
  • Deuterium exchange
  • Deutero-1-pentene
  • Fischer-Tropsch
  • Hydrogenation

ASJC Scopus subject areas

  • Catalysis
  • General Chemistry

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