TY - JOUR
T1 - Dichloridobis(3,4,5-trimethyl-1H-pyrazole-Nκ2)cobalt(II)
AU - Lyubartseva, Ganna
AU - Parkin, Sean
PY - 2010/9
Y1 - 2010/9
N2 - In the title compound, [CoIICl2(C6H 10N2)2], a pair of 3,4,5-trimethylpyrazoles act as monodentate ligands. Two Cl- anions are also bonded directly to the CoII atom, which has a CoN2Cl2 chromophore in a slightly distorted tetrahedral geometry. The two molecules in the asymmetric unit are related by an approximate twofold rotation roughly parallel to the a axis. The amino H atom in the pyrazole ring participates in weak N-H⋯Cl hydrogen bonds to form chains that propagate roughly parallel to the c axis.
AB - In the title compound, [CoIICl2(C6H 10N2)2], a pair of 3,4,5-trimethylpyrazoles act as monodentate ligands. Two Cl- anions are also bonded directly to the CoII atom, which has a CoN2Cl2 chromophore in a slightly distorted tetrahedral geometry. The two molecules in the asymmetric unit are related by an approximate twofold rotation roughly parallel to the a axis. The amino H atom in the pyrazole ring participates in weak N-H⋯Cl hydrogen bonds to form chains that propagate roughly parallel to the c axis.
UR - http://www.scopus.com/inward/record.url?scp=77956305704&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=77956305704&partnerID=8YFLogxK
U2 - 10.1107/S160053681003254X
DO - 10.1107/S160053681003254X
M3 - Article
C2 - 21588534
AN - SCOPUS:77956305704
SN - 1600-5368
VL - 66
SP - m1134
JO - Acta Crystallographica Section E: Structure Reports Online
JF - Acta Crystallographica Section E: Structure Reports Online
IS - 9
ER -