Direct intramolecular carbon(sp2)-nitrogen(sp2) reductive elimination from gold(iii)

Jong Hyun Kim, R. Tyler Mertens, Amal Agarwal, Sean Parkin, Gilles Berger, Samuel G. Awuah

Research output: Contribution to journalArticlepeer-review

18 Scopus citations

Abstract

The reactivity of bidentate AuIII-Cl species, [(C^N)AuCl2], with a bisphosphine or carbon donor ligands results in reductive elimination. Combined experimental and computational investigations lead to the first evidence of a direct intramolecular C(sp2)-N(sp2) bond formation from a monomeric [(C^N)AuCl2] gold(iii) complex. We show that bidentate ligated Au(iii) systems bypass transmetallation to form C(sp2)-N(sp2) species and NHC-Au-Cl. Mechanistic investigations of the reported transformation reveal a ligand-induced reductive elimination via a key AuIII intermediate. Kinetic studies of the reaction support a second-order rate process.

Original languageEnglish
Pages (from-to)6273-6282
Number of pages10
JournalDalton Transactions
Volume48
Issue number18
DOIs
StatePublished - 2019

Bibliographical note

Publisher Copyright:
© The Royal Society of Chemistry 2019.

ASJC Scopus subject areas

  • Inorganic Chemistry

Fingerprint

Dive into the research topics of 'Direct intramolecular carbon(sp2)-nitrogen(sp2) reductive elimination from gold(iii)'. Together they form a unique fingerprint.

Cite this