Abstract
The direct observation of Li diffusion in Li-doped zinc oxide nanowires (NWs) was realized by using in situ heating in the scanning transmission electron microscope (STEM). A continuous increase of low atomic mass regions within a single NW was observed between 200 ° C and 600 ° C when heated in vacuum, which was explained by the conversion of interstitial to substitutional Li in the ZnO NW host lattice. A kick-out mechanism is introduced to explain the migration and conversion of the interstitial Li (Lii) to Zn-site substitutional Li (LiZn), and this mechanism is verified with low-temperature (11 K) photoluminescence measurements on as-grown and annealed Li-doped zinc oxide NWs, as well as the observation of an increase of NW surface roughing with applied bias.
Original language | English |
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Article number | 054001 |
Journal | Materials Research Express |
Volume | 3 |
Issue number | 5 |
DOIs | |
State | Published - May 2016 |
Bibliographical note
Publisher Copyright:© 2016 IOP Publishing Ltd.
ASJC Scopus subject areas
- Electronic, Optical and Magnetic Materials
- Biomaterials
- Surfaces, Coatings and Films
- Polymers and Plastics
- Metals and Alloys