Dual emission from a family of conjugated dinuclear RuII complexes

Edith C. Glazer; Douglas Magde; Yitzhak Tor

doi:10.1021/ja0440304

Dual emission from a family of conjugated dinuclear Ru^II complexes

Edith C. Glazer, Douglas Magde, Yitzhak Tor

Chemistry

Research output: Contribution to journal › Article › peer-review

85 Scopus citations

Abstract

Dual emission is observed from a family of simple acetylene-linked dinuclear Ru^II complexes, where two MLCT excited states coexist at room temperature and in fluid solution. This unique behavior is attributed to a specific substitution pattern on the bridging ligand and provides the opportunity to investigate the structural and electronic features that result in decoupling of standard nonradiative decay pathways.

Original language	English
Pages (from-to)	4190-4192
Number of pages	3
Journal	Journal of the American Chemical Society
Volume	127
Issue number	12
DOIs	https://doi.org/10.1021/ja0440304
State	Published - Mar 30 2005

ASJC Scopus subject areas

Catalysis
Chemistry (all)
Biochemistry
Colloid and Surface Chemistry

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title = "Dual emission from a family of conjugated dinuclear RuII complexes",

abstract = "Dual emission is observed from a family of simple acetylene-linked dinuclear RuII complexes, where two MLCT excited states coexist at room temperature and in fluid solution. This unique behavior is attributed to a specific substitution pattern on the bridging ligand and provides the opportunity to investigate the structural and electronic features that result in decoupling of standard nonradiative decay pathways.",

author = "Glazer, {Edith C.} and Douglas Magde and Yitzhak Tor",

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T1 - Dual emission from a family of conjugated dinuclear RuII complexes

AU - Glazer, Edith C.

AU - Magde, Douglas

AU - Tor, Yitzhak

PY - 2005/3/30

Y1 - 2005/3/30

N2 - Dual emission is observed from a family of simple acetylene-linked dinuclear RuII complexes, where two MLCT excited states coexist at room temperature and in fluid solution. This unique behavior is attributed to a specific substitution pattern on the bridging ligand and provides the opportunity to investigate the structural and electronic features that result in decoupling of standard nonradiative decay pathways.

AB - Dual emission is observed from a family of simple acetylene-linked dinuclear RuII complexes, where two MLCT excited states coexist at room temperature and in fluid solution. This unique behavior is attributed to a specific substitution pattern on the bridging ligand and provides the opportunity to investigate the structural and electronic features that result in decoupling of standard nonradiative decay pathways.

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U2 - 10.1021/ja0440304

DO - 10.1021/ja0440304

M3 - Article

C2 - 15783199

AN - SCOPUS:16244407376

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EP - 4192

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 12

ER -

Dual emission from a family of conjugated dinuclear Ru^II complexes

Abstract

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