Dynamics of the evaporative dewetting of a volatile liquid film confined within a circular ring

Wei Sun, Fuqian Yang

Research output: Contribution to journalArticlepeer-review

8 Scopus citations

Abstract

The dewetting dynamics of a toluene film confined within a copper ring on a deformable PMMA film is studied. The toluene film experiences evaporation and dewetting, which leads to the formation of a circular contact line around the center of the copper ring. The contact line recedes smoothly toward the copper ring at a constant velocity until reaching a dynamic "stick" state to form the first circular polymer ridge. The average receding velocity is found to be dependent on the dimensions of the copper ring (the copper ring diameter and the cross-sectional diameter of the copper wire) and the thickness of the PMMA films. A model is presented to qualitatively explain the evaporative dewetting phenomenon.

Original languageEnglish
Pages (from-to)4024-4031
Number of pages8
JournalLangmuir
Volume31
Issue number13
DOIs
StatePublished - Mar 18 2015

Bibliographical note

Publisher Copyright:
© 2015 American Chemical Society.

ASJC Scopus subject areas

  • General Materials Science
  • Condensed Matter Physics
  • Surfaces and Interfaces
  • Spectroscopy
  • Electrochemistry

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